84702-76-1Relevant articles and documents
Manganese-catalyzed oxidative azidation of cyclobutanols: Regiospecific synthesis of alkyl azides by C-C bond cleavage
Ren, Rongguo,Zhao, Huijun,Huan, Leitao,Zhu, Chen
supporting information, p. 12692 - 12696 (2015/10/28)
A novel, manganese-catalyzed oxidative azidation of cyclobutanols is described. A wide range of primary, secondary, and tertiary alkyl azides were generated in synthetically useful yields and exclusive regioselectivity. Aside from linear alkyl azides, oth
Copper/HP20: Novel and polymer-supported copper catalyst for huisgen cycloaddition
Kitamura, Yoshiaki,Taniguchi, Kazumi,Maegawa, Tomohiro,Monguchi, Yasunari,Kitade, Yukio,Sajiki, Hironao
experimental part, p. 521 - 532 (2009/09/06)
A polymer-supported copper catalyst (Cu/HP20) is easily prepared in water and effectively catalyzed the Huisgen cycloaddition between azides and terminal alkynes.
Hammett correlation of nornicotine analogues in the aqueous aldol reaction: Implications for green organocatalysis
Rogers, Claude J.,Dickerson, Tobin J.,Brogan, Andrew P.,Janda, Kim D.
, p. 3705 - 3708 (2007/10/03)
(Chemical Equation Presented) A series of meta- and para-substituted 2-arylpyrrolidines were synthesized and examined for their ability to catalyze an aqueous aldol reaction under buffered conditions. Kinetic analysis of arylpyrrolidine-catalyzed reactions displayed a linear Hammett correlation with ρ = 1.14 (R2 = 0.996), indicating that the reaction is accelerated by electron-withdrawing aryl rings. These results show promise for the development of a synthetically viable aqueous organocatalyst.
