847225-59-6

Basic information

• Product Name: Carbamic acid, [3-[[(2-nitro-3-pyridinyl)oxy]methyl]phenyl]-, 1,1-dimethylethyl ester
• CAS NO: 847225-59-6
• Molecular Formula: C17H19N3O5
• Molecular Weight: 345.355
• Mol File: 847225-59-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Carbamic acid, [3-[[(2-nitro-3-pyridinyl)oxy]methyl]phenyl]-, 1,1-dimethylethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, [3-[[(2-nitro-3-pyridinyl)oxy]methyl]phenyl]-, 1,1-dimethylethyl ester(847225-59-6)
• EPA Substance Registry System: Carbamic acid, [3-[[(2-nitro-3-pyridinyl)oxy]methyl]phenyl]-, 1,1-dimethylethyl ester(847225-59-6)

Safety Data

• Hazardous Substances Data: 847225-59-6(Hazardous Substances Data)

Upstream product

• 74037-50-6 3-ethoxy-2-nitropyridine 
• 15128-82-2 3-hydroxy-2-nitropyridine 
• 118684-31-4 tert-butyl N-[3-(hydroxymethyl)phenyl]carbamate 

Downstream Products

• 847225-57-4 2-nitro-3-(3-aminobenzyloxy)pyridine 

Relevant articles and documents

Tetrabutylammonium salt induced denitration of nitropyridines: Synthesis of fluoro-, hydroxy-, and methoxypyridines

(Chemical Equation Presented) An efficient method for the synthesis of fluoropyridines via the fluorodenitration reaction is reported. The reaction is mediated by tetrabutylammonium fluoride (TBAF) under mild conditions without undue regard to the presence of water. The fluorodenitration is general for 2- or 4-nitro-substituted pyridines, while 3-nitropyridines require attendant electron-withdrawing groups for the reaction to proceed efficiently. Nitropyridines also undergo hydroxy- and methoxydenitration under mild conditions in the presence of the corresponding tetrabutylammonium species.