847749-07-9

Basic information

• Product Name: (Pd(C₆H₃(O(CH₂)9CH₃)CHNC₆H₄O(CH₂)9CH₃)OCOCH₂O(CH₂CH₂O)2CH₃)2
• CAS NO: 847749-07-9
• Molecular Weight: 1552.73
• Mol File: 847749-07-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Pd(C₆H₃(O(CH₂)9CH₃)CHNC₆H₄O(CH₂)9CH₃)OCOCH₂O(CH₂CH₂O)2CH₃)2(CAS DataBase Reference)
• NIST Chemistry Reference: (Pd(C₆H₃(O(CH₂)9CH₃)CHNC₆H₄O(CH₂)9CH₃)OCOCH₂O(CH₂CH₂O)2CH₃)2(847749-07-9)
• EPA Substance Registry System: (Pd(C₆H₃(O(CH₂)9CH₃)CHNC₆H₄O(CH₂)9CH₃)OCOCH₂O(CH₂CH₂O)2CH₃)2(847749-07-9)

Safety Data

• Hazardous Substances Data: 847749-07-9(Hazardous Substances Data)

Upstream product

• 16024-58-1 2-[2-(2-methoxyethoxy)etoxy]acetic acid 

Relevant articles and documents

Mesogens based on palladium orthometallated complexes with carboxylato bridges: Tuning and shaping a non-planar molecule

The binuclear cyclopalladated compounds [Pd2(μ-OH) 2(Ln)2] (1) derived from imines HLn = p-CnH2n + 1O-C6H4-CHN-C 6H4-OCnH2n + 1-p (n = 6,10) react with carboxylic acids to give the derivatives [Pd2(μ-ox) 2(Ln)2] (2) with a planar core for oxalic acid, and [Pd2(μ-OOCR)2(Ln)2] (3-7) compounds with a non-planar ridge tent structure for other RCOOH acids: (3) R = CmH2m + 1 (m = 1, 3, 5, 7, 9, 11, 13, 15, 17); (4) R = CH2(OCH2CH2)pOCH3 (p = 1, 2); (5) R = CH2-C6H4-OCqH 2q + 1-p (q = 2, 4, 6, 8, 10, 12); (6) R = C6H 4-OCrH2r + 1-p (r = 4, 10); (7) R = C*H(OH)CH3. The acids used were designed to explore the effect on the thermal properties of the compounds prepared of systematic variations in the type of carboxylato ligand, which induce structure, packing, and polarity changes, and in the length of the carboxylato chain. Most of the complexes prepared, even when far from planar, show liquid crystal behavior and display nematic, smectic A and smectic C phases.