848649-91-2

Basic information

• Product Name: 2H-INDOLE-2-THIONE, 5-BROMO-1,3-DIHYDRO-
• Synonyms: 2H-INDOLE-2-THIONE, 5-BROMO-1,3-DIHYDRO-
• CAS NO: 848649-91-2
• Molecular Formula: C₈H₆BrNS
• Molecular Weight: 228.10894
• Mol File: 848649-91-2.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2H-INDOLE-2-THIONE, 5-BROMO-1,3-DIHYDRO-(CAS DataBase Reference)
• NIST Chemistry Reference: 2H-INDOLE-2-THIONE, 5-BROMO-1,3-DIHYDRO-(848649-91-2)
• EPA Substance Registry System: 2H-INDOLE-2-THIONE, 5-BROMO-1,3-DIHYDRO-(848649-91-2)

Safety Data

• Hazardous Substances Data: 848649-91-2(Hazardous Substances Data)

Upstream product

• 20870-78-4 5-bromo-2-indolin-2-one 
• 87-48-9 5-Bromo-1H-indole-2,3-dione 

Relevant articles and documents

Nickel(ii)-catalyzed asymmetric thio-Claisen rearrangement of α-diazo pyrazoleamides with thioindoles

A nickel(ii) catalyzed enantioselective thio-Claisen rearrangement of α-diazo pyrazoleamides with thioindoles was realized with modified chiral N,N′-dioxide ligands, affording a variety of C3-substituted indole derivatives in high yields (up to 95%) with excellent enantioselectivities (up to 96% ee) under mild reaction conditions. A possible transition state model was proposed based on previous reports and the X-ray crystal structure of the catalyst.