84988-35-2Relevant articles and documents
Assembling capacity of P/N ligands derived from bicyclic aminophosphoranes: Obtaining di- and trimetallic iron nitrosyls
Mordenti, Laurence,Roustan, Jean-Louis,Riess, Jean G.
, p. 843 - 845 (2008/10/08)
Bicyclic aminophosphorane 2, PhPH(OCH2CH2)2N, displaces one or two carbonyl groups of Fe(CO)2(NO)2 to yield P-only-bonded adducts 4 and 5 of the monocyclic open form 1, PhP(OCH2CH2)2NH. These adducts further react through their uncoordinated NH sites with [Fe(NO)2I]2 to yield di- and trimetallic iron nitrosyl compounds 10 and 11 in high yields.