850130-96-0Relevant articles and documents
The central role of the metal ion for photoactivity: Zn-vs.Ni-Mabiq
Block, Matthias,Derondeau, Henrieta,Esezobor, Oaikhena Z.,Hauer, Jürgen,Hess, Corinna R.,Jandl, Christian,Kaila, Ville R. I.,Lauenstein, Raphael,Mader, Sophie L.,R?mer, Armin J.,Riedle, Eberhard,Thyrhaug, Erling
, p. 7521 - 7532 (2021)
Photoredox catalysts are integral components of artificial photosystems, and have recently emerged as powerful tools for catalysing numerous organic reactions. However, the development of inexpensive and efficient earth-abundant photoredox catalysts remai
Visible-light induced Cross-Dehydrogenative-Coupling (CDC) reactions of N-aryl tetrahydroisoquinolines under aerobic conditions
Lin, Chao,Li, Peiwu,Wang, Lin
, (2021/05/19)
A visible-light induced cross-dehydrogenative-coupling (CDC) reaction of N-aryl tetrahydroisoquinolines was developed under mild aerobic conditions. This protocol proceeded smoothly with a large range of nucleophiles (nitroalkane, dimethyl phosphite, dimethyl malonate, N-methyl indole, TMSCN) under metal-free conditions and an oxygen atmosphere, forming a new C–C bond. Visible-light played a significant acceleration effect in this reaction.
Cyanine-based near infra-red organic photoredox catalysis
Baralle, Alexandre,Cormier, Morgan,Goddard, Jean-Philippe,Obah Kosso, Anne Roly,Sellet, Nicolas
, p. 6964 - 6968 (2021/06/02)
Direct metal-free near infra-red photoredox catalysis is applied to organic oxidation, photosensitization and reduction, involving cyanines as photocatalysts. This photocatalyst is competitive with conventional reactions catalyzed under visible light. Kin