85150-76-1Relevant articles and documents
A practical synthesis and X-ray crystal structure of tribenzo[ a, d, j ]corannulene
Smith, Natalie J.,Scott, Lawrence T.
, p. 410 - 414 (2016)
Tribenzo[a,d,j]corannulene (5) has been synthesized in four linear steps from commercially available starting materials on a half-gram scale in 18% overall yield. An X-ray crystal structure of this triply benzannulated geodesic polyarene confirms the prediction that successive benzannulation of corannulene has a gradual flattening effect on the bowl-shaped core.
Palladium-Catalyzed [5 + 2] Heteroannulation of Phenethylamides with 1,3-Dienes to Dopaminergic 3-Benzazepines
Saá, Carlos,Varela, Jesús A.,Velasco-Rubio, álvaro
supporting information, p. 3591 - 3595 (2020/05/01)
Phenethyltriflamides react with 1,3-dienes upon treatment with a catalytic amount of Pd(OAc)2 and Cu(OAc)2/O2 as oxidant to afford chemo-, regio- A nd diastereoselectively 2,3,4,5-tetrahydro-1H-benzo[d]azepines (3-benzazepine derivatives) in good to excellent yields. A DFT study of the [5 + 2] heteroannulation suggests a mechanistic pathway starting with formation of the six-membered palladacycle cis-PdX2L2 via a CMD process followed by ??2 coordination and insertion of the 1,3-diene unit in a diastereoselective manner.
Nickel catalyzed electrosynthesis of ketones from organic halides and metal carbonyls
Dolhem,Ocafrain,Nedelec,Troupel
, p. 17089 - 17096 (2007/10/03)
Ketones can be easily obtained by electroreduction in an undivided cell of an organic halide-metal carbonyl mixture using a Ni-bpy catalytic system in DMF (bpy = 2,2'-bipyridine). The process is especially well convenient for primary benzyl and alkyl halides.
