851530-55-7

Basic information

• Product Name: [(p-CF₃-C₆H₄)3P]2 bis(pivalate) rhodium(I)Ph
• Synonyms: [(p-CF₃-C₆H₄)3P]2 bis(pivalate) rhodium(I)Ph
• CAS NO: 851530-55-7
• Molecular Weight: 1314.83
• Mol File: 851530-55-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(p-CF₃-C₆H₄)3P]2 bis(pivalate) rhodium(I)Ph(CAS DataBase Reference)
• NIST Chemistry Reference: [(p-CF₃-C₆H₄)3P]2 bis(pivalate) rhodium(I)Ph(851530-55-7)
• EPA Substance Registry System: [(p-CF₃-C₆H₄)3P]2 bis(pivalate) rhodium(I)Ph(851530-55-7)

Safety Data

• Hazardous Substances Data: 851530-55-7(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 63902-12-5 [RhCl(cis-cyclooctene)2]2 
• 13406-29-6 tris(para-trifluoromethyl)phenyl phosphine 

Relevant articles and documents

Direct C-arylation of free (NH)-indoles and pyrroles catalyzed by Ar-Rh(III) complexes assembled in situ

Ar-Rh(III) pivalate complexes assembled in situ from the reaction of [RhCl(coe)2]2 (coe = cis-cyclooctene), [p-(CF3)C6H4]3P, and CsOPiv effectively catalyzed the direct C-arylation of free (NH)-indoles and (NH)-pyrroles in good yields and with high regioselectivity. The reaction displayed excellent functional group compatibility and low moisture sensitivity. Kinetics studies support a mechanism involving phosphine displacement by indole in complex 2 (resting state of the catalyst), followed by a rate-limiting C-H bond metalation. Copyright