851591-16-7

Basic information

• Product Name: (4′-methoxylbiphenyl-2-yl)(phenyl)methanone
• Synonyms: (4′-methoxylbiphenyl-2-yl)(phenyl)methanone
• CAS NO: 851591-16-7
• Molecular Weight: 288.346
• Mol File: 851591-16-7.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: (4′-methoxylbiphenyl-2-yl)(phenyl)methanone(CAS DataBase Reference)
• NIST Chemistry Reference: (4′-methoxylbiphenyl-2-yl)(phenyl)methanone(851591-16-7)
• EPA Substance Registry System: (4′-methoxylbiphenyl-2-yl)(phenyl)methanone(851591-16-7)

Safety Data

• Hazardous Substances Data: 851591-16-7(Hazardous Substances Data)

Upstream product

• 125610-78-8 4'-methoxybiphenyl-2-carbonitrile 
• 591-51-5 phenyllithium 
• 4387-36-4 2-iodobenzonitrile 
• 3930-83-4 o-iodobenzamide 
• 609-67-6 2-Iodobenzoyl chloride 
• 88-67-5 2-Iodobenzoic acid 
• 5162-03-8 (2-chlorophenyl)(phenyl)methanone 
• 93296-09-4 4-methoxyphenylzinc chloride 
• 342-24-5 o-fluorobenzophenone 
• 13047-06-8 o-bromobenzophenone 
• 5720-07-0 4-methoxyphenylboronic acid 
• 2835-77-0 (2-aminophenyl)(phenyl)methanone 
• 117-99-7 2-Hydroxybenzophenone 
• 104-92-7 1-bromo-4-methoxy-benzene 

Downstream Products

• 913369-53-6 4-methoxy-2'-(α-hydroxybenzyl)biphenyl 
• 1520098-08-1 (Z)-1,2-bis[4'-methoxy-(1,1'-biphenyl)-4-yl]-1,2-diphenylethene 
• 95128-27-1 3-methoxy-6-phenylphenanthridine 

Relevant articles and documents

6-Arylphenanthridines from Aryl o-Biaryl Ketones with 1,1,1,3,3,3-Hexamethyldisilazane and Molecular Iodine

Warming treatment of aryl o-biaryl ketones with 1,1,1,3,3,3-hexamethyldisilazane in the presence of Sc(OTf)3 in toluene, followed by the reaction with molecular iodine and K2CO3 in a mixture of THF and methanol at 60 °C gave the corresponding 6-arylphenanthridines in good to moderate yields. The present reaction is a one-pot method for the preparation of 6-arylphenanthridines from aryl o-biaryl ketones through the cyclization of imino-nitrogen-centered radicals that were generated from N-iodo aryl o-biaryl ketimines formed from the reaction of aryl biaryl ketimines with molecular iodine.

P,N,N-Pincer nickel-catalyzed cross-coupling of aryl fluorides and chlorides

P,N,N-Pincer nickel complexes [Ni(Cl){N(2-R2PC6H 4)(2′-Me2NC6H4)}] (R = Ph, 3a; R = Pri, 3b; R = Cy, 3c) were synthesized and their catalysis toward the Kumada or Negishi cross-coupling reaction of aryl fluorides and chlorides was evaluated. Complex 3a effectively catalyzes the cross-coupling of (hetero)aryl fluorides with aryl Grignard reagents at room temperature. Complex 3a also catalyzes the cross-coupling of (hetero)aryl chlorides and arylzinc reagents at 80 °C with low catalyst loadings and good functional group compatibility. the Partner Organisations 2014.

Stereoselective synthesis of folded luminogens with arene-arene stacking interactions and aggregation-enhanced emission

Tetraphenylethene derivatives with a folded Z-conformation and aggregation-enhanced emission characteristics are synthesized from 2-arylbenzophenones. The intramolecular rotation of the folded luminogens is partially suppressed, resulting in improved emission efficiencies in solutions.