85185-31-5

Basic information

• Product Name: 1,3-Benzodioxole, 5-(4-phenyl-1-butenyl)-, (Z)-
• CAS NO: 85185-31-5
• Molecular Formula: C17H16O2
• Molecular Weight: 252.313
• Mol File: 85185-31-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,3-Benzodioxole, 5-(4-phenyl-1-butenyl)-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Benzodioxole, 5-(4-phenyl-1-butenyl)-, (Z)-(85185-31-5)
• EPA Substance Registry System: 1,3-Benzodioxole, 5-(4-phenyl-1-butenyl)-, (Z)-(85185-31-5)

Safety Data

• Hazardous Substances Data: 85185-31-5(Hazardous Substances Data)

Upstream product

• 82895-48-5 1,2-methylenedioxy-4-(phenylsulfonylmethyl)benzene 
• 120-57-0 piperonal 
• 7484-37-9 (3-phenylpropyl)triphenylphosphonium bromide 

Relevant articles and documents

A New Synthesis of Olefins via the Elimination Reaction of β-Tributylstannyl Organosulfur Compounds

Organosulfur compounds on treatment with butyllithium in tetrahydrofuran followed by tributylstannylmethyl iodide 1 afforded olefins.The reaction was found to proceed via the destannylsulfurization of the initially formed β-stannyl organosulfur compounds.Thus, allyl 2-pyridyl sulfides 2 or allyl phenyl sulfones 12 were converted into 1,3-dienes 4.Compounds 13 and 15 were converted into the olefins 14 and 17.Furthermore, the reaction was applied to the synthesis of α-substituted vinyl sulfides 24 and allene 27.The stereochemistry of the double bond is discussed.Keywords - destannylsulfurization; allyl 2-pyridyl sulfide; allyl phenyl sulfone; synthesis of olefin; 1,3-diene; vinyl sulfide; β-tributylstannyl organosulfur compound.