853748-90-0

Basic information

• Product Name: (2-butyl-1-p-tolyl-hex-2-enyloxy)-triethyl-silane
• Synonyms: (2-butyl-1-p-tolyl-hex-2-enyloxy)-triethyl-silane
• CAS NO: 853748-90-0
• Molecular Weight: 360.656
• Mol File: 853748-90-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2-butyl-1-p-tolyl-hex-2-enyloxy)-triethyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: (2-butyl-1-p-tolyl-hex-2-enyloxy)-triethyl-silane(853748-90-0)
• EPA Substance Registry System: (2-butyl-1-p-tolyl-hex-2-enyloxy)-triethyl-silane(853748-90-0)

Safety Data

• Hazardous Substances Data: 853748-90-0(Hazardous Substances Data)

Upstream product

• 853748-87-5 (S)-non-5-yn-4-ol 
• 617-86-7 triethylsilane 
• 104-87-0 4-methyl-benzaldehyde 
• 821-74-9 (Sa)-nona-4,5-diene 

Relevant articles and documents

Enantioselective and regioselective nickel-catalyzed multicomponent coupling of chiral allenes, aromatic aldehydes, and silanes

A detailed account of the development of a recently developed, nickel-catalyzed multicomponent coupling of chiral allenes, aromatic aldehydes, and silanes is described. The axial chirality of the allene is transferred completely to the product, a trisubstituted Z-allylic alcohol protected as a silyl ether. A very high preference for sp rather than sp2 coupling is observed, and differentially substituted allenes undergo highly site-selective coupling. These transformations represent the first enantioselective multi-component coupling processes of allenes.