85413-87-2

Basic information

• Product Name: N'-N-Diethyl-N'-,N'-dimethyl-methanediamine
• Synonyms: N'-N-Diethyl-N'-,N'-dimethyl-methanediamine
• CAS NO: 85413-87-2
• Molecular Weight: 130.233
• Mol File: 85413-87-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N'-N-Diethyl-N'-,N'-dimethyl-methanediamine(CAS DataBase Reference)
• NIST Chemistry Reference: N'-N-Diethyl-N'-,N'-dimethyl-methanediamine(85413-87-2)
• EPA Substance Registry System: N'-N-Diethyl-N'-,N'-dimethyl-methanediamine(85413-87-2)

Safety Data

• Hazardous Substances Data: 85413-87-2(Hazardous Substances Data)

Upstream product

• 1353053-97-0 triethylsiloxymethyl-N,N-dimethylamine 
• 109-89-7 diethylamine 
• 80202-60-4 N-<(trimethylsiloxy)methyl>dimethylamine 
• 996-50-9 N,N-diethyl-1,1,1-trimethylsilanamine 

Relevant articles and documents

Siloxymethylamines as Aminomethylation Reagents for Amines Leading to Labile Diaminomethanes That can be Trapped as Their [Mo(CO)4] Complexes

Compound Et3SiOCH2NMe2 transfers Me2NCH2 to R2NH (R2=Et2, PhMe, [Cr(η6-C6H5)(CO)3]Me, PhH) to form previously unknown diaminomethanes, Me2NCH2NR2 and, in the case of R2=PhH, the triamine Me2NCH2N(Ph)CH2NMe2. The diaminomethanes exhibit an unreported disproportionation to a mixture of (R2N)2CH2, (Me2N)2CH2, and Me2NCH2NR2, which can be trapped as their [Mo(CO)4(diamine)] complexes. Whereas PhMeNCH2NMe2 is a labile material, the metal-substituted ([(η6-C6H5)Cr(CO)3]MeNCH2NMe2 is a stable material. The triamine Me2NCH2N(Ph)CH2NMe2 is unstable with respect to transformation to 1,3,5-triphenyltriazine, but is readily trapped as the bidentate-triamineMo(CO)4. All metal complexes were characterized by single-crystal X-ray diffraction.