854375-11-4Relevant articles and documents
Remote stereocontrol by sulfinyl groups: Hydrocyanation of δ-ketosulfoxides
García Ruano, José L.,Fernández-Ibá?ez, M. ángeles,Maestro, M. Carmen,Rodríguez-Fernández, M. Mercedes
, p. 1245 - 1252 (2007/10/03)
Reactions of (2-p-tolylsulfinyl)benzyl alkyl (and aryl) ketones (δ-ketosulfoxides) with Et2AlCN in the presence of Yb(OTf) 3 take place in a completely stereoselective manner, demonstrating the efficiency of the sulfinyl group in the