85620-82-2Relevant articles and documents
Novel catalysis of dendrimer-bound Pd(0) complexes: Sterically steered allylic amination and the first application for a thermomorphic system
Mizugaki, Tomoo,Murata, Makoto,Ooe, Masahiko,Ebitani, Kohki,Kaneda, Kiyotomi
, p. 52 - 53 (2002)
Phosphinated dendrimer-bound Pd(0) complex catalysts show high stereoselectivity for allylic amination due to the surface congestion of dendrimers and can be easily recycled without loss of activity under thermomorphic conditions.
Self-assembled Dendrimer-bound Pd(II) Complexes via Acid-base Interactions and their Catalysis for Allylic Amination
Ooe, Masahiko,Murata, Makoto,Takahama, Atsushi,Mizugaki, Tomoo,Ebitani, Kohki,Kaneda, Kiyotomi
, p. 692 - 693 (2003)
The Pd complexes were noncovalently attached on the periphery of poly(propyleneimine) dendrimers based on acid-base interactions. The dendritic Pd complexes were found to possess catalytic activities for allylic amination, and to be able to mimick the cat
B(C6F5)3-catalyzed tandem protonation/deuteration and reduction of: In situ -formed enamines
Wu, Rongpei,Gao, Ke
, p. 4032 - 4036 (2021/05/19)
A highly efficient B(C6F5)3-catalyzed tandem protonation/deuteration and reduction of in situ-formed enamines in the presence of water and pinacolborane was developed. Regioselective β-deuteration of tertiary amines was achieved with high chemo- and regioselectivity. D2O was used as a readily available and cheap source of deuterium. Mechanistic studies indicated that B(C6F5)3 could activate water to promote the protonation and reduction of enamines. This journal is
4-Amino-3-pentadecyl-3H-1,2,4-triazole-3-thiones and 3-pentadecyl-1,3,4-oxadiazole-2(3H)-thione for the preparation of dimeric palladium(II) complexes and their applications in Tsuji–Trost and Mizoroki–Heck reactions
Chehrouri, Manel,Othman, Adil A.,Jiménez-Cecilia, Samuel,Moreno-Cabrerizo, Cristina,Sansano, José M.
supporting information, p. 1301 - 1307 (2019/04/27)
The synthesis of palladium complexes derived from 4-amino-3-pentadecyl-3H-1,2,4-triazole-3-thiones and 3-pentadecyl-1,3,4-oxadiazole-2(3H)-thiones are reported. They were obtained from palladium acetate and dipotassium tetrachloropalladate(II) and their composition was assigned by elemental analysis (solid state). The resulting metallic entities were also characterized in solution based in mass spectrometry experiments. Their application in organic synthesis as cross-coupling reaction catalysts is described. One example of both conventional Tsuji–Trost and Mizoroki–Heck reactions were efficiently carried out in very high chemical yield.