856834-88-3 Usage
General Description
2-(2-Bromoethyl)-6-methylpyridine is a chemical compound with the molecular formula C8H10BrN. It is a derivative of pyridine, containing a bromoethyl group attached to the 2-position and a methyl group attached to the 6-position. 2-(2-BROMOETHYL)-6-METHYLPYRIDINE is commonly used as a building block in the synthesis of pharmaceuticals, agrochemicals, and other organic compounds. It is a colorless to yellow liquid with a strong, unpleasant odor and is highly flammable. The chemical properties and reactivity of 2-(2-Bromoethyl)-6-methylpyridine make it an important intermediate in the production of various fine chemicals.
Check Digit Verification of cas no
The CAS Registry Mumber 856834-88-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 8,5,6,8,3 and 4 respectively; the second part has 2 digits, 8 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 856834-88:
(8*8)+(7*5)+(6*6)+(5*8)+(4*3)+(3*4)+(2*8)+(1*8)=223
223 % 10 = 3
So 856834-88-3 is a valid CAS Registry Number.
856834-88-3Relevant articles and documents
Radical Hydroarylation of Functionalized Olefins and Mechanistic Investigation of Photocatalytic Pyridyl Radical Reactions
Seath, Ciaran P.,Vogt, David B.,Xu, Zihao,Boyington, Allyson J.,Jui, Nathan T.
supporting information, p. 15525 - 15534 (2018/11/23)
We report the photoredox alkylation of halopyridines using functionalized alkene and alkyne building blocks. Selective single-electron reduction of the halogenated pyridines provides the corresponding heteroaryl radicals, which undergo anti-Markovnikov addition to the alkene substrates. The system is shown to be mild and tolerant of a variety of alkene and alkyne subtypes. A combination of computational and experimental studies support a mechanism involving proton-coupled electron transfer followed by medium-dependent alkene addition and rapid hydrogen atom transfer mediated by a polarity-reversal catalyst.
