85689-10-7

Basic information

• Product Name: exo-2-(4-Methoxyphenylsulfonyloxy)-1-azabicyclo<2.2.1>heptan
• Synonyms: exo-2-(4-Methoxyphenylsulfonyloxy)-1-azabicyclo<2.2.1>heptan
• CAS NO: 85689-10-7
• Molecular Weight: 283.348
• Mol File: 85689-10-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: exo-2-(4-Methoxyphenylsulfonyloxy)-1-azabicyclo<2.2.1>heptan(CAS DataBase Reference)
• NIST Chemistry Reference: exo-2-(4-Methoxyphenylsulfonyloxy)-1-azabicyclo<2.2.1>heptan(85689-10-7)
• EPA Substance Registry System: exo-2-(4-Methoxyphenylsulfonyloxy)-1-azabicyclo<2.2.1>heptan(85689-10-7)

Safety Data

• Hazardous Substances Data: 85689-10-7(Hazardous Substances Data)

Upstream product

• 85689-01-6 2-Azabicyclo<2.2.1>heptan-2-ol 
• 98-68-0 4-methoxy-phenyl-sulphonyl chloride 

Relevant articles and documents

Nitrenium and Carbenium Ions in Rearrangements of 2-Azabicyclic Systems

An ionic mechanism proceeding in intimate ion pairs is suggested for the rearrangement of N-sulfonyloxy derivatives of 2-azabicycloheptane and -hept-5-ene (e. g. 9, 11 -> 10, 12). 1.Experiments with 18O labelled educts show partial scrambling dependend both on structure of educt and solvent. 2.In methanol the intermediate carbenium ions (19, 23) react to give methoxy compounds. 3.MINDO/3-calculations are in agreement with the experiments: a) In the saturated systems the nitrenium ion 20 is a stable intermediate. b) The optimized geometries of the rearranged carbenium ions (21, 23) are consistent with the products obtained in methanol.