857062-41-0Relevant articles and documents
A highly efficient synthesis of rocaglaols by a novel α-arylation of ketones
Diedrichs, Nicole,Ragot, Jacques P.,Thede, Kai
, p. 1731 - 1735 (2007/10/03)
Rocaglaols are natural products exhibiting a range of biological activities. A new synthetic method for the α-arylation of ketones allows for the synthesis of previously inaccessible rocaglaol derivatives. The key sequence consists of a previously unreported Suzuki type reaction using brominated si-lyl enol ethers as substrates followed by deprotection of the arylated silyl enol ethers. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005.