85711-95-1

Basic information

• Product Name: (Z)-hex-3-enyl undec-10-enoate
• Synonyms: (Z)-hex-3-enyl undec-10-enoate;10-Undecenoic acid (Z)-3-hexenyl ester;Einecs 288-354-4
• CAS NO: 85711-95-1
• Molecular Formula: C17H30O2
• Molecular Weight: 266.4189
• EINECS: 288-354-4
• Mol File: 85711-95-1.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 343.5°C at 760 mmHg
• Flash Point: 98°C
• Appearance: /
• Density: 0.884g/cm³
• Vapor Pressure: 7.01E-05mmHg at 25°C
• Refractive Index: 1.458
• CAS DataBase Reference: (Z)-hex-3-enyl undec-10-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-hex-3-enyl undec-10-enoate(85711-95-1)
• EPA Substance Registry System: (Z)-hex-3-enyl undec-10-enoate(85711-95-1)

Safety Data

• Hazardous Substances Data: 85711-95-1(Hazardous Substances Data)

Usage

Description

(Z)-hex-3-enyl undec-10-enoate is a chemical compound that belongs to the class of esters. It is formed by the combination of the unsaturated fatty acid undec-10-enoic acid and the alcohol (Z)-hex-3-enol. (Z)-hex-3-enyl undec-10-enoate is characterized by its fruity, floral, and green odor, making it a versatile ingredient in various industries.

Uses

Used in the Food Industry:
(Z)-hex-3-enyl undec-10-enoate is used as a flavoring agent for its fruity, floral, and green aroma, enhancing the taste and smell of various food products.
Used in the Perfume and Fragrance Industry:
(Z)-hex-3-enyl undec-10-enoate is used as a key component in the production of perfumes and fragrances, capitalizing on its pleasant and distinctive scent to create appealing scents for consumers.
Used in the Natural Products Industry:
(Z)-hex-3-enyl undec-10-enoate can be found in various natural sources, such as fruits and flowers, contributing to their unique and attractive odors. It is also synthesized for commercial purposes to meet the demands of different industries that rely on its sensory properties.

InChI:InChI=1/C17H30O2/c1-3-5-7-9-10-11-12-13-15-17(18)19-16-14-8-6-4-2/h3,6,8H,1,4-5,7,9-16H2,2H3/b8-6+

Upstream product

• 38460-95-6 undec-10-enoyl chloride 
• 928-96-1 (Z)-3-Hexen-1-ol 
• 928-97-2 (E)-3-hexen-1-ol 

Relevant articles and documents

USING STEREORETENTION FOR THE SYNTHESIS OF E-MACROCYCLES WITH RUTHENIUM-BASED OLEFIN METATHESIS CATALYSTS

This invention relates generally to the synthesis of E-macrocycles using stereoretentive ruthenium olefin metathesis catalysts supported by dithioiate ligands. Macrocycles were generated with excellent selectivity (>99% E) and in moderate to high/good yields (47% to 80% yield; 58% to 80% yield) from diene starting materials bearing two E-olefins or bearing one E- olefin and one terminal olefin, A variety of rings were constructed, ranging from 12- to 18- membered macrocycles, including the antibiotic recifeiolide. The invention has utility in the fields of organometallics and organic synthesis.

A HIGHLY EFFICIENT SYNTHESIS OF Z-MACROCYCLES USING STEREORETENTIVE, RUTHENIUM-BASED METATHESIS CATALYSTS

A highly efficient, Z-selective ring-closing metathesis system for the formation of macrocycles using a stereoretentive, ruthenium-based catalyst supported by a dithiolate ligand is reported. This catalyst is demonstrated to be remarkably active as observed in initiation experiments showing complete catalyst initiation at - 20°C within 10 min. Using easily accessible diene starting materials bearing a Z-olefin moiety, macrocyclization reactions generated products with significantly higher Z-selectivity in appreciably shorter reaction times, in higher yield, and with much lower catalyst loadings than in previously reported systems. Macrocyclic lactones ranging in size from twelve-mem bered to seventeen-membered rings are synthesized in moderate to high yields (68 - 79% yield) with excellent Z-selectivity (95% - 99% Z).