85733-65-9Relevant articles and documents
Iron Complexes of N-Substituted Thiosalicylideneimines. Part 1. Synthesis and Reactions with Oxygen and Carbon Monoxide
Marini, Peter J.,Murray, Keith S.,West, Bruce O.
, p. 143 - 152 (2007/10/02)
Iron(II) complexes with N-substituted bidentate and tetradentate thiosalicylideneimines can be prepared by the reaction of bis(thiosalicylaldehydato)iron(II) with appropriate primary amines.The bidentate compounds show S = 2 spin states while a number of the tetradentate compounds have the unusual S = 1 state.The tetradentate complexes react with CO to form monocarbonyl complexes and with O2 to form FeIII μ-oxo-bridged derivatives.Some evidence is presented to support the preliminary formation at low temperatures of a dinuclear iron(III) peroxo-species as the precursor of the μ-oxo-compounds.Several spin-paired FeIII compounds containing SN2-bonded tridentate ligands are also reported.