857894-31-6

Basic information

• Product Name: (R)-(-)-7-benzyloxyheptylidene-p-toluenesulfonimide
• Synonyms: (R)-(-)-7-benzyloxyheptylidene-p-toluenesulfonimide
• CAS NO: 857894-31-6
• Molecular Weight: 357.517
• Mol File: 857894-31-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-(-)-7-benzyloxyheptylidene-p-toluenesulfonimide(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-(-)-7-benzyloxyheptylidene-p-toluenesulfonimide(857894-31-6)
• EPA Substance Registry System: (R)-(-)-7-benzyloxyheptylidene-p-toluenesulfonimide(857894-31-6)

Safety Data

• Hazardous Substances Data: 857894-31-6(Hazardous Substances Data)

Upstream product

• 141943-06-8 1,7-heptanediol monobenzyl ether 
• 129649-05-4 7-benzyloxyheptan-1-ol 
• 247089-85-6 (R)-p-toluenesulfinamide 

Downstream Products

• 857894-36-1 (R)-(+)-6-(6-benzyloxyhexyl)-4-(tert-butyldimethylsilanyloxy)-5,6-dihydro-2H-pyridine-1,3-dicarboxylic acid 1-tert-butyl ester 3-methyl ester 
• 857894-35-0 (6R)-(+)-6-(6-benzyloxyhexyl)-4-hydroxy-5,6-dihydro-2H-pyridine-1,3-dicarboxylic acid 1-tert-butyl ester 3-methyl ester 
• 857894-33-8 (R_SR,R)-(-)-methyl 3-oxo-5-(6-benzyloxyhexyl)-5-(p-toluenesulfinylamino)pentanoate 
• 857894-34-9 (R)-(-)-6-(6-benzyloxyhexyl)-4-oxo-5,6-dihydro-4H-pyridine-1,3-dicarboxylic acid 1-tert-butyl ester 3-methyl ester 
• 857894-32-7 (R_SR,R)-(-)-methyl 3-(6-benzyloxyhexyl)-3-(p-toluenesulfinylamino)propanoate 

Relevant articles and documents

Asymmetric synthesis of 2,4,5-trisubstituted piperidines from sulfinimine-derived δ-amino β-ketoesters. Formal synthesis of pseudodistomin B triacetate

N-Sulfinyl δ-amino β-ketoester enaminones, a new sulfinimine-derived chiral building block, undergoes, on hydrolysis in one pot, an intramolecular Michael addition followed by a retro-Michael-type elimination to give enantiopure 2,4,5-trisubstituted piper