85797-15-5Relevant articles and documents
Biosynthesis and metabolism of dolichosterone in arabidopsis thaliana
Lee, Sang Cheul,Hwang, Jung-Yun,Joo, Se-Hwan,Son, Seung-Hyun,Youn, Ji Hyun,Kim, Seong-Ki
experimental part, p. 3475 - 3478 (2012/05/07)
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Stereoselective Synthesis of the Plant-growth-promoting Steroids Dolicholide and Dolichosterone
Takatsuto, Suguru,Ikekawa, Nobuo
, p. 2133 - 2137 (2007/10/02)
Stereoselective syntheses of dolicholide (3), (22R,23R)-2α,3α,22,23-tetrahydroxy-B-homo-7-oxa-5α-ergost-24(28)-en-6-one, and dolichosterone (4), (22R,23R)-2α,3α,22,23-tetrahydroxy-5α-ergost-24(28)-en-6-one, were achieved from the known (22E,24S)-2α,3α-diacetoxy-5α-stigmast-22-en-6-one (5) which is readily available from stigmasterol.The key step in the construction of the (22R,23R)-vicinal diol function in the steroidal side-chain was new and used the method of chelation control.