85864-85-3Relevant articles and documents
Synthesis of 2-hydroxy-8′-(hydroxymethyl)-1,1′-binaphthalene (iso-homo-binol). A new structural pattern in the binaphthyl realm
Vyskocil, Stepan,Lockhart, Stephen C.,Mitchell, William L.,Kocovsky, Pavel
, p. 907 - 916 (2007/10/03)
The title compound 7 has been synthesized in a racemic form, using Suzuki coupling (8 + 15 → 16) as the key step. Pure enantiomer (S)-(-)-7 has been obtained by carbonylation of the known bromide (S)-(+)-12 followed by reduction of the resulting methyl ester (S)-(+)-18 with LiAlH4.