85894-91-3

Basic information

• Product Name: Benzene, [[1-(phenylmethyl)ethenyl]thio]-
• CAS NO: 85894-91-3
• Molecular Formula: C15H14S
• Molecular Weight: 226.342
• Mol File: 85894-91-3.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzene, [[1-(phenylmethyl)ethenyl]thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [[1-(phenylmethyl)ethenyl]thio]-(85894-91-3)
• EPA Substance Registry System: Benzene, [[1-(phenylmethyl)ethenyl]thio]-(85894-91-3)

Safety Data

• Hazardous Substances Data: 85894-91-3(Hazardous Substances Data)

Upstream product

• 10147-11-2 propargyl benzene 
• 108-98-5 thiophenol 
• 54905-12-3 (2-phenylethane-1,1-diyl)bis(phenylsulfane) 
• 2327-99-3 1-phenylpropadiene 
• 100-39-0 benzyl bromide 
• 1822-73-7 phenylthioethylene 

Downstream Products

• 85895-07-4 dimethyl (E)-(2-(phenylthio)-3-phenyl-2-propenyl)malonate 
• 85895-08-5 dimethyl (Z)-(2-(phenylthio)-3-phenyl-2-propenyl)malonate 
• 85895-59-6 (Z)-1-phenyl-2-(phenylthio)-3-bromoprop-1-ene 
• 85895-58-5 (E)-1-phenyl-2-(phenylthio)-3-bromoprop-1-ene 

Relevant articles and documents

Highly regioselective addition of benzenethiol to allenes catalyzed by palladium acetate

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Hydroxo-rhodium-N-heterocyclic carbene complexes as efficient catalyst precursors for alkyne hydrothiolation

The new Rh-hydroxo dinuclear complexes stabilized by an N-heterocyclic carbene (NHC) ligand of type [Rh(μ-OH)(NHC)(η2-olefin)] 2 (coe, IPr (3), IMes (4); ethylene, IPr (5)) are efficient catalyst precursors for alkyne hydrothiolation

A New Synthesis of Olefins via the Elimination Reaction of β-Tributylstannyl Organosulfur Compounds

Organosulfur compounds on treatment with butyllithium in tetrahydrofuran followed by tributylstannylmethyl iodide 1 afforded olefins.The reaction was found to proceed via the destannylsulfurization of the initially formed β-stannyl organosulfur compounds.Thus, allyl 2-pyridyl sulfides 2 or allyl phenyl sulfones 12 were converted into 1,3-dienes 4.Compounds 13 and 15 were converted into the olefins 14 and 17.Furthermore, the reaction was applied to the synthesis of α-substituted vinyl sulfides 24 and allene 27.The stereochemistry of the double bond is discussed.Keywords - destannylsulfurization; allyl 2-pyridyl sulfide; allyl phenyl sulfone; synthesis of olefin; 1,3-diene; vinyl sulfide; β-tributylstannyl organosulfur compound.