859103-39-2

Basic information

• Product Name: 3-hydroxy-5-(4-methoxybenzyloxy)-benzoic acid ethyl ester
• Synonyms: 3-hydroxy-5-(4-methoxybenzyloxy)-benzoic acid ethyl ester
• CAS NO: 859103-39-2
• Molecular Weight: 302.327
• Mol File: 859103-39-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-hydroxy-5-(4-methoxybenzyloxy)-benzoic acid ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-hydroxy-5-(4-methoxybenzyloxy)-benzoic acid ethyl ester(859103-39-2)
• EPA Substance Registry System: 3-hydroxy-5-(4-methoxybenzyloxy)-benzoic acid ethyl ester(859103-39-2)

Safety Data

• Hazardous Substances Data: 859103-39-2(Hazardous Substances Data)

Upstream product

• 99-10-5 3,5-Dihydroxybenzoic acid 
• 4142-98-7 ethyl 3,5-dihydroxybenzoate 
• 824-94-2 p-methoxybenzyl chloride 

Downstream Products

• 859102-93-5 3-(dimethoxyphosphoryloxy)-5-(4-methoxybenzyloxy)-benzoic acid ethyl ester 

Relevant articles and documents

Synthesis of a tetrasubstituted arylphosphonate via the anionic phospho-Fries rearrangement

The anionic phospho-Fries rearrangement of phosphoric acid (3,5-di-isopropoxy)phenyl ester diethyl ester (11) gave rise to (2-hydroxy-4,6-di-isopropoxy-phenyl)phosphonic acid diethyl ester (12) in excellent yield. The phenol functionality of 12 was converted to the corresponding triflate which was coupled with vinyltributylstannane, under Stille conditions, to give a styrene. This molecule is intended to serve as the aromatic fragment in the synthesis of a phosphorus-based transition-state analogue for the hydrolysis of the S-(-)-zearalenone lactone.