85943-26-6

Basic information

• Product Name: 5-(TERT-BUTYL)-2-METHOXYBENZENECARBALDEHYDE
• Synonyms: TIMTEC-BB SBB010873;ASINEX-REAG BAS 11412115;5-(TERT-BUTYL)-2-METHOXYBENZALDEHYDE;5-(TERT-BUTYL)-2-METHOXYBENZENECARBALDEHYDE;4-(tert-Butyl)-2-formylanisole, 5-(tert-Butyl)-o-anisaldehyde;2-Methoxy-5-tert-butylbenzaldehyde;Benzaldehyde, 5-(1,1-dimethylethyl)-2-methoxy-;5-Tbu-2-meo-benzaldehyde
• CAS NO: 85943-26-6
• Molecular Formula: C₁₂H₁₆O₂
• Molecular Weight: 192.25
• Mol File: 85943-26-6.mol
• Article Data: 10

Chemical Properties

• Melting Point: 32 °C
• Boiling Point: 281.5°C at 760 mmHg
• Flash Point: 113.4°C
• Appearance: /
• Density: 1.002g/cm³
• Vapor Pressure: 0.00355mmHg at 25°C
• Refractive Index: 1.517
• Storage Temp.: Inert atmosphere,Room Temperature
• Solubility: Chloroform (Slightly), Ethyl Acetate (Slightly)
• CAS DataBase Reference: 5-(TERT-BUTYL)-2-METHOXYBENZENECARBALDEHYDE(CAS DataBase Reference)
• NIST Chemistry Reference: 5-(TERT-BUTYL)-2-METHOXYBENZENECARBALDEHYDE(85943-26-6)
• EPA Substance Registry System: 5-(TERT-BUTYL)-2-METHOXYBENZENECARBALDEHYDE(85943-26-6)

Safety Data

• Hazard Codes: Xi
• HazardClass: IRRITANT
• Hazardous Substances Data: 85943-26-6(Hazardous Substances Data)

Usage

Description

5-(TERT-BUTYL)-2-METHOXYBENZENECARBALDEHYDE is an organic compound that serves as a versatile reagent in the synthesis of various materials, including conjugated polymers and fluorescent sensors.

Uses

Used in Polymer Synthesis:
5-(TERT-BUTYL)-2-METHOXYBENZENECARBALDEHYDE is used as a reagent in the preparation of conjugated polymers, which are essential for applications in organic electronics, such as organic light-emitting diodes (OLEDs), organic photovoltaics (OPVs), and organic field-effect transistors (OFETs). Its unique structure contributes to the desired electronic and optical properties of these polymers.
Used in Fluorescent Sensor Development:
5-(TERT-BUTYL)-2-METHOXYBENZENECARBALDEHYDE is also used as a reagent for the development of highly selective fluorescent sensors. These sensors are crucial in various analytical and diagnostic applications, including environmental monitoring, medical diagnostics, and chemical sensing. 5-(TERT-BUTYL)-2-METHOXYBENZENECARBALDEHYDE's specific chemical properties enable the creation of sensors with high sensitivity and selectivity for target analytes.

InChI:InChI=1/C12H16O2/c1-12(2,3)10-5-6-11(14-4)9(7-10)8-13/h5-8H,1-4H3

Upstream product

• 22252-73-9 2-chloromethyl-4-tert-butylanisole 
• 100-97-0 hexamethylenetetramine 
• 2591-86-8 N-Formylpiperidine 
• 5396-38-3 1-(tert-butyl)-4-methoxybenzene 
• 74-88-4 methyl iodide 
• 2725-53-3 2-hydroxy-5-t-butylbenzaldehyde 
• 77-78-1 dimethyl sulfate 
• 68-12-2 N,N-dimethyl-formamide 

Downstream Products

• 99758-66-4 5-(tert-butyl)-2-methoxy-3-nitrobenzaldehyde 
• 6621-77-8 2-Methoxy-5-tert-butyl-benzaldehyd-octadecylthiosemicarbazon 
• 127491-63-8 (Z)-2-Acetylamino-3-(5-tert-butyl-2-methoxy-phenyl)-acrylic acid 
• 182007-00-7 (5-tert-butyl-2-methoxyphenyl)phenylmethanol 
• 182007-01-8 bis(5-tert-butyl-2-methoxyphenyl)methanol 
• 782460-66-6 α-(5-t-butyl-2-methoxyphenyl)-N-phenyl nitrone 
• 5409-99-4 5-tert-butyl-2-methoxy-benzophenone 
• 98085-84-8 2,2'-Dimethoxy-5,5'-di-tert-butyldiphenylmethane 
• 182007-03-0 Bis-(5-tert-butyl-2-methoxy-phenyl)-phenyl-methanol 
• 127516-86-3 3-(5-tert-Butyl-2-methoxy-phenyl)-2-oxo-propionic acid 
• 1180663-44-8 3-(5-tert-butyl-2-methoxyphenyl)acrylic acid 

Relevant articles and documents

INTEGRIN ANTAGONISTS

The present disclosure provides pharmaceutical agents, including those of the formula:(I) wherein the variables are defined herein. Also provided are pharmaceutical compositions, kits and articles of manufacture comprising such pharmaceutical agents. Meth

Nucleophilic Amination of Methoxy Arenes Promoted by a Sodium Hydride/Iodide Composite

A method for the nucleophilic amination of methoxy arenes was established by using sodium hydride (NaH) in the presence of lithium iodide (LiI). This method offers an efficient route to benzannulated nitrogen heterocycles. Mechanistic studies showed that the reaction proceeds through an unusual concerted nucleophilic aromatic substitution.

Unsymmetric salen ligands bearing a Lewis base: Intramolecularly cooperative catalysis for cyanosilylation of aldehydes

A series of unsymmetric salen ligands derived from 1,2-diaminocyclohexane bearing an appended Lewis base on the three-position of one aromatic ring were synthesized by the reaction of various functional salicyaldehydes with the condensation product of 1,2-diaminocyclohexane mono(hydrogen chloride) and 3,5-di-tert-butylsalicylaldehyde. These ligands in conjunction with Ti(O iPr)4 exhibited excellent activity in catalyzing the cyanosilylation of aldehydes with trimethylsilyl cyanide (TMSCN) at mild conditions. The highest activity was observed in the catalyst system with regard to the salen ligand bearing a diethylamino group, which proved to be active even at a high [aldehyde]/[catalyst] ratio up to 50000. In a low catalyst loading of 0.05 mol%, the quantitative conversion of benzaldehyde to the corresponding cyanosilylation product was found within 10 min. at ambient temperature. An intramolecularly cooperative catalysis was proposed wherein the central metal Ti(iv) is suggested to play a role of Lewis acid to activate aldehydes while the appended Lewis base to activate TMSCN.