859838-47-4Relevant articles and documents
A practical synthesis of 2-azidoethyl α-glycosides: useful spacer-arm glycosides for the synthesis of neoglycoconjugates
Sharma, Gangavaram V. M.,Krishna, Palakodety Radha
, p. 393 - 398 (1993)
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Conjugates of polyhedral boron compounds with carbohydrates. 2. Unexpected easy closo- to nido-transformation of a carborane-carbohydrate conjugate in neutral aqueous solution
Kononov, Leonid O.,Orlova, Anna V.,Zinin, Alexander I.,Kimel, Boris G.,Sivaev, Igor B.,Bregadze, Vladimir I.
, p. 2769 - 2774 (2007/10/03)
A novel 1,2-dicarba-closo-dodecaborane-lactose conjugate 4c, when dissolved in water or methanol, is subject to unexpected deboronation in neutral conditions leading to the formation of the corresponding nido-counterpart (5) as detected by 11B NMR spectroscopy. After heating the aqueous solution of the conjugate 4c at 60 °C for 17 h pure 1,2-dicarba-nido-undecaborane- lactose conjugate 5 was obtained.