86-59-9 Usage
Chemical Properties
white to light yellow crystal powder
Uses
Different sources of media describe the Uses of 86-59-9 differently. You can refer to the following data:
1. 8-Quinolinecarboxylic acid may be used in the synthesis of novel oxorhenium(V) complexes incorporating quinoline and isoquinoline carboxylic acid derivatives, chiral 1,2,3,4-tetrahydroquinolinyl-oxazoline compounds, used as ligands for Ru-catalyzed asymmetric transfer hydrogenation of ketones and chiral quinolinyl-oxazoline compounds, used as ligands for Cu(II) catalyzed asymmetric cyclopropanation.
2. 8-Quinolinecarboxylic acid may be used in the synthesis of:novel oxorhenium(V) complexes incorporating quinoline and isoquinoline carboxylic acid derivativeschiral 1,2,3,4-tetrahydroquinolinyl-oxazoline compounds, used as ligands for Ru-catalyzed asymmetric transfer hydrogenation of ketoneschiral quinolinyl-oxazoline compounds, used as ligands for Cu(II) catalyzed asymmetric cyclopropanation
General Description
Herbicide 8-quinolinecarboxylic acid and its removal from aqueous solution using sodium montmorillonite, acidic montmorillonite and organo-acidic montmorillonite has been reported.
Purification Methods
Crystallise the acid from water, aqueous EtOH, EtOH or *C6H6. The ethyl ester has m 45o and b 194-197o/13mm. [Beilstein 22 H 81, 22 III/IV 1200, 22/3 V 217.]
Check Digit Verification of cas no
The CAS Registry Mumber 86-59-9 includes 5 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 2 digits, 8 and 6 respectively; the second part has 2 digits, 5 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 86-59:
(4*8)+(3*6)+(2*5)+(1*9)=69
69 % 10 = 9
So 86-59-9 is a valid CAS Registry Number.
InChI:InChI=1/C10H7NO2/c12-10(13)8-5-1-3-7-4-2-6-11-9(7)8/h1-6H,(H,12,13)/p-1
86-59-9Relevant articles and documents
Synthesis derivatives of 2-amino-4-quinolones from 1,2,3,4- tetrahydroquinoline-8-carboxylic acids
Listunov, Dimitriy,Popov, Kirill,Tkachuk, Tetyana,Volovenko, Yulian
, p. 660 - 662 (2013)
A simple and efficient method is developed. Novel 2-amino-4-quinolone derivatives are synthesized. The products that have several functional groups for possible future modifications are described.
Redox couple involving NOx in aerobic Pd-catalyzed oxidation of sp3-C-H bonds: Direct Evidence for Pd-NO3-/NO2- interactions involved in oxidation and reductive elimination
Wenzel, Margot N.,Owens, Philippa K.,Bray, Joshua T.W.,Lynam, Jason M.,Aguiar, Pedro M.,Reed, Christopher,Lee, James D.,Hamilton, Jacqueline F.,Whitwood, Adrian C.,Fairlamb, Ian J.S.
, p. 1177 - 1190 (2017/05/16)
NaNO3 is used in oxidative Pd-catalyzed processes as a complementary co-catalyst to common oxidants, e.g., CuII salts, in C-H bond activation and Wacker oxidation processes. NaNO3 and NaNO2 (with air or O2
Insertion of an Alkene into an ester: Intramolecular oxyacylation reaction of alkenes through acyl C-O bond activation
Hoang, Giang T.,Reddy, Venkata Jaganmohan,Nguyen, Huy H. K.,Douglas, Christopher J.
supporting information; experimental part, p. 1882 - 1884 (2011/04/16)
Atom economy and esters: compatible now! The first catalytic insertion of a C-C bond into an acyl C-O bond was achieved using rhodium catalysts (see scheme). The products are β-alkoxy ketones with a fully substituted carbon center. Quinoline chelating groups were employed to stabilize the Rh-alkoxide intermediate.
