86000-10-4Relevant articles and documents
Trifluoromethanesulfonic Acid-Promoted Reaction of Hexahydro-1,3,5-triazines. Introduction of a Secondary Aminomethyl Grouping into Carboxylates at the α-Position through Ketene Silyl Acetals
Ikeda, Kiyoshi,Achiwa, Kazuo,Sekiya, Minoru
, p. 1579 - 1583 (2007/10/02)
Introduction of secondary aminomethyl grouping RNHCH2 into carboxylates at the α-position has been achieved by reaction of hexahydro-1,3,5-triazines with ketene silyl acetals in the presence of a catalytic amount of trifluoromethanesulfonic acid.Keywords
TRIFLUOROMETHANESULFONIC ACID-PROMOTED REACTION OF HEXAHYDRO-1,3,5-TRIAZINES WITH KETENE SILYL ACETALS. CONVENIENT SYNTHESIS OF ALKYL β-AMINOCARBOXYLATES
Ikeda, Kiyoshi,Achiwa, Kazuo,Sekiya, Minoru
, p. 913 - 916 (2007/10/02)
A new, convenient synthesis of alkyl β-aminocarboxylates has been achieved by a reaction of hexahydro-1,3,5-triazines with ketene silyl acetals in the presence of catalytic amount of trifluoromethanesulfonic acid.