86091-69-2

Basic information

• Product Name: L-Leucine, N-(3,5-dinitrobenzoyl)-, methyl ester
• CAS NO: 86091-69-2
• Molecular Formula: C14H17N3O7
• Molecular Weight: 339.305
• Mol File: 86091-69-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: L-Leucine, N-(3,5-dinitrobenzoyl)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: L-Leucine, N-(3,5-dinitrobenzoyl)-, methyl ester(86091-69-2)
• EPA Substance Registry System: L-Leucine, N-(3,5-dinitrobenzoyl)-, methyl ester(86091-69-2)

Safety Data

• Hazardous Substances Data: 86091-69-2(Hazardous Substances Data)

Upstream product

• 74928-54-4 3,5-(NO2)2C6H3CONHCH(CH2CH(CH3)2)COOH 
• 77-78-1 dimethyl sulfate 
• 67-56-1 methanol 
• 7495-01-4 (S)-N-(3,5-dinitrobenzoyl)leucine 

Relevant articles and documents

Biphasic enantioselective partitioning studies using small-molecule chiral selectors

Enantioselective partitioning of racemic N-3,5-(dinitrobenzoyl)leucine or racemic naproxen was studied using a two-component chiral phase transfer approach. A combination of an achiral ion-pairing reagent and a chiral complexing agent (selector) is necessary to effect enantioselective partitioning between an aqueous bicarbonate solution and a nonpolar organic solvent. In these biphasic resolutions, the interplay between the ion-pairing reagent and the selector is essential for maximizing enantioselectivities. Furthermore, the lipophilicity of the ion-pairing reagent, the concentration of the ion-pairing reagent and selector, and the polarity of the organic solvent all exert a considerable influence on the biphasic process. In this manuscript, we conduct optimization studies through analysis of solvent, concentration and ion-pairing effects. Conclusions concerning the mechanistic rationale behind enantioselective partitioning are given.

Enantioselective and Diastereoselective Binding Study of Silica Bound Macrobicyclic Receptors by HPLC

-