861145-57-5Relevant articles and documents
Stereospecific radical polymerization of substituted benzyl muconates in the solid state under topochemical control
Matsumoto, Akikazu,Tanaka, Toshihiro,Oka, Kunio
, p. 1479 - 1490 (2005)
We have successfully controlled the stereochemical structure of diene polymers during radical polymerization in the solid state under UV and γ-ray radiation. The polymerization of the substituted benzyl muconates occurred via a crystal lattice controlled reaction mechanism. The polymerization is controlled by not only diisotactic and disyndiotactic, but also meso and racemo structures to afford various kinds of stereoregular polymers. Georg Thieme Verlag Stuttgart.