861316-23-6

Basic information

• Product Name: 1-benzylcyclohexane-1,2-diol
• Synonyms: 1-benzylcyclohexane-1,2-diol
• CAS NO: 861316-23-6
• Molecular Weight: 206.285
• Mol File: 861316-23-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-benzylcyclohexane-1,2-diol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-benzylcyclohexane-1,2-diol(861316-23-6)
• EPA Substance Registry System: 1-benzylcyclohexane-1,2-diol(861316-23-6)

Safety Data

• Hazardous Substances Data: 861316-23-6(Hazardous Substances Data)

Upstream product

• 533-60-8 cyclohexanone-2-ol 
• 6921-34-2 benzylmagnesium chloride 
• 100-44-7 benzyl chloride 
• 108-94-1 cyclohexanone 
• 945-49-3 cyclohexylphenylmethanol 
• 60-29-7 diethyl ether 
• 861316-39-4 1-benzyl-2-iodo-cyclohexanol 
• 946-33-8 2-benzylcyclohexan-1-one 
• 67-64-1 acetone 
• 60278-07-1 2-benzyl-2-hydroxycyclohexan-1-one 
• 4714-09-4 1-benzylcyclohexene 

Downstream Products

• 28994-41-4 o-Benzylphenol 
• 946-33-8 2-benzylcyclohexan-1-one 

Relevant articles and documents

Regioselective 1,2-Diol Rearrangement by Controlling the Loading of BF3·Et2O and Its Application to the Synthesis of Related Nor-Sesquiterene- and Sesquiterene-Type Marine Natural Products

The regiocontrolled rearrangement of 1,2-diols has been achieved by controlling the loading of BF3·Et2O. Its applicability is showcased by the divergent synthesis of austrodoral, austrodoric acid, and 8-epi-11-nordriman-9-one, as well as a formal synthesis of siphonodictyal B and liphagal. A new light is shed on piancol-type rearrangements that will be useful in diversity-oriented synthesis of related natural products.