86151-59-9Relevant articles and documents
m-Iodosylbenzoic acid, a tagged hypervalent iodine reagent for the iodo-functionalization of alkenes and alkynes
Yusubov, Mekhman S.,Yusubova, Roza Ya.,Kirschning, Andreas,Park, Joo Yeon,Chi, Ki-Whan
, p. 1506 - 1509 (2008/09/19)
An efficient and facile method for the iodo-functionalization of alkenes 5 and alkynes 6 by using recyclable m-iodosylbenzoic acid (2) was developed. The final products can be easily isolated without any chromatographic purification by simple treatment of the crude mixture with an anionic exchange resin. Unreacted m-iodosylbenzoic acid and reduced m-iodobenzoic acid are effectively recovered from the resin by acidification with hydrochloric acid.
Halofluorination of Alkenes Using Dilute Hydrofluoric Acid
Kuroboshi, Manabu,Hiyama, Tamejiro
, p. 1799 - 1806 (2007/10/03)
Iodofluorination of alkenes was achieved with N-iodosuccinimide, potassium hydrogendifluoride, and 1 M hydrofluoric acid using tetrabutylammonium fluoride as a phase-transfer catalyst.The active fluorinating reagent was shown to be tetrabutylammonium dihy
A CONVENIENT SYNTHETIC METHOD OF 1,3-DISUBSTITUTED ISOQUINOLINES USING SILVER TRIFLUOROMETHANESULFONATE AS A KEY REAGENT
Sato, Tadashi,Tamura, Kunio,Nagayoshi, Kazuo
, p. 791 - 794 (2007/10/02)
1,3-Disubstituted isoquinolines were prepared under mild conditions from allylbenzenes and nitriles using silver trifluoromethanesulfonate and iodine.
