861605-94-9

Basic information

• Product Name: 4-bromo-2-phenoxybenzoic acid
• Synonyms: 4-bromo-2-phenoxybenzoic acid
• CAS NO: 861605-94-9
• Molecular Formula: C13H9BrO3
• Molecular Weight: 293.117
• Mol File: 861605-94-9.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: 4-bromo-2-phenoxybenzoic acid(CAS DataBase Reference)
• NIST Chemistry Reference: 4-bromo-2-phenoxybenzoic acid(861605-94-9)
• EPA Substance Registry System: 4-bromo-2-phenoxybenzoic acid(861605-94-9)

Safety Data

• Hazardous Substances Data: 861605-94-9(Hazardous Substances Data)

Upstream product

• 1133123-02-0 4-bromo-2- iodobenzoic acid 
• 1093418-75-7 methyl 4-bromo-2-iodobenzoate 
• 20776-50-5 2-amino-4-bromobenzoic acid 
• 1016313-33-9 C₁₄H₁₁BrO₃ 
• 105942-08-3 4-bromo-6-fluorobenzonitrile 
• 2243-42-7 2-phenoxybenzoic acid 
• 118-55-8 phenyl Salicylate 
• 108-95-2 phenol 
• 540-38-5 p-Iodophenol 
• 59748-90-2 4-Bromo-2-chloro-benzoic Acid 
• 78471-43-9 methyl 4-bromo-2-(bromomethyl)benzoate 
• 875664-25-8 4-bromo-2-phenoxy-benzonitrile 
• 611-00-7 2,4-dibromobenzoic acid 
• 139-02-6 sodium phenoxide 

Downstream Products

• 99515-51-2 phenyl 4-bromo-2-hydroxybenzoate 
• 26608-06-0 3-bromodibenzofuran 
• 500286-36-2 3-bromo-9H-xanthene-9-one 

Relevant articles and documents

Electrochemical Reductive Smiles Rearrangement for C-N Bond Formation

A conceptually new and synthetically valuable radical Smiles rearrangement reaction is reported under undivided electrolytic conditions. This protocol employs an entirely new strategy for the electrochemical radical Smiles rearrangement. Remarkably, an amidyl radical generated from the cleavage of the N-O bond under reductive electrolytic conditions plays a crucial role in this transformation. Various hydroxylamine derivatives bearing different substituents are suitable in this electrochemical transformation, furnishing the corresponding amides in up to 86% yield.

Anthraquinone organic electroluminescent material and application thereof

The invention discloses an anthraquinone organic electroluminescent material and application thereof. A general formula compound is shown in a formula (1) in the specification, and in the formula (1),Z is selected from O or S; X1-X8 are independently selected from CR1 or N, wherein R1 is selected from a structure shown in a formula (2) in the specification, or selected from hydrogen, alkyl, arylor heterocyclic aryl, adjacent R1 groups can form a ring, and at least one of R1 groups is selected from the structure (2) shown in the formula (2); in the formula (2), Y1-Y8 are independently selected from CR2 or N, and at least one of the Y1-Y8 is selected from N; R2 is selected from hydrogen, alkyl, aryl or heterocyclic aryl, and adjacent R2 groups can form a ring; L is selected from single bonds, arylidene or heterocyclic arylidene; and when two or more R1 groups are selected from the formula (2), the selected L groups in the formula (2) are not single bonds at the same time. The compoundshows excellent device performance and stability when serving as the light-emitting material in an organic light-emitting device (OLED), and meanwhile the OLED adopting the general formula compound iswithin the scope of right protection.

A photoredox-neutral Smiles rearrangement of 2-aryloxybenzoic acids

We report on the use of visible light photoredox catalysis for the radical Smiles rearrangement of 2-aryloxybenzoic acids to obtain aryl salicylates. The method is free of noble metals and operationally simple and the reaction can be run under mild batch or flow conditions. Being a redox neutral process, no stoichiometric oxidants or reductants are needed.