86429-24-5

Basic information

• Product Name: 1-(chlorophenylboryl)-1-phenyl-2-(trimethylsilyl)-1-hexene
• Synonyms: 1-(chlorophenylboryl)-1-phenyl-2-(trimethylsilyl)-1-hexene
• CAS NO: 86429-24-5
• Molecular Weight: 354.803
• Mol File: 86429-24-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(chlorophenylboryl)-1-phenyl-2-(trimethylsilyl)-1-hexene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(chlorophenylboryl)-1-phenyl-2-(trimethylsilyl)-1-hexene(86429-24-5)
• EPA Substance Registry System: 1-(chlorophenylboryl)-1-phenyl-2-(trimethylsilyl)-1-hexene(86429-24-5)

Safety Data

• Hazardous Substances Data: 86429-24-5(Hazardous Substances Data)

Upstream product

• 3844-94-8 1-(trimethylsilyl)-1-hexyne 
• 3677-81-4 diphenylboronchloride 

Downstream Products

• 942-92-7 caprophenone 

Relevant articles and documents

Boration Reactions with 1-Alkynes

Halodiorganoboranes R2BHal(R = Et, Ph) as well as benzyldihaloboranes PhCH2BHal2 undergo a regiospecific addition to the triple-bond of 1-alkynes ACCR'.The reversible haloboration (1) gives Z-alkenes as the more stable isomers.At elevated temperatures, the irreversible 1,1-organoboration (2) predominates, accompanied by a 1,2-transfer of A, whereas the 1,2-organoboration (3) is observed only as an unimportant side-reaction in a few cases.The cyclisation (4) occurs as a sequence of cis-haloboration and intramolecular aromatic alkenylation in the case of PhCH2BCl2 as borating agent.