86429-26-7

Basic information

• Product Name: (+/-)-3,3-dimethyl-2-phenylbutanal
• Synonyms: (+/-)-3,3-dimethyl-2-phenylbutanal
• CAS NO: 86429-26-7
• Molecular Weight: 176.258
• Mol File: 86429-26-7.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: (+/-)-3,3-dimethyl-2-phenylbutanal(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-3,3-dimethyl-2-phenylbutanal(86429-26-7)
• EPA Substance Registry System: (+/-)-3,3-dimethyl-2-phenylbutanal(86429-26-7)

Safety Data

• Hazardous Substances Data: 86429-26-7(Hazardous Substances Data)

Upstream product

• 5676-29-9 (3,3-dimethylbut-1-en-2-yl)benzene 
• 591-51-5 phenyllithium 
• 21811-48-3 3,3-dimethyl-2-phenyl-butan-2-ol 
• 75-97-8 3,3-dimethyl-butan-2-one 
• 938-16-9 2,2-dimethylpropiophenone 
• 136175-22-9 2-tert-butyl-2-phenyl-1-(4-tolylsulfonyl)aziridine 
• 107847-16-5 (+/-)-2-(1,1-dimethylethyl)-2-phenyloxirane 
• 189025-08-9 3,3-Dimethyl-2-phenyl-1-butanol 
• 917-92-0 3,3-Dimethylbut-1-yne 
• 5123-17-1 bromodiphenylborane 
• 3677-81-4 diphenylboronchloride 

Downstream Products

• 938-16-9 2,2-dimethylpropiophenone 
• 1198158-13-2 2-fluoro-3,3-dimethyl-2-phenylbutyraldehyde 
• 114245-65-7 (E)-(4RS)-5,5-dimethyl-1,4-diphenylhex-2-en-1-one 
• 114245-64-6 (E)-(6RS)-2,2,7,7-tetramethyl-6-phenyloct-4-en-3-one 
• 107847-33-6 (5SR,6SR)-5-hydroxy-2,2,7,7-tetramethyl-6-phenyloctan-3-one 
• 107847-33-6 (5RS,6SR)-5-hydroxy-2,2,7,7-tetramethyl-6-phenyloctan-3-one 

Relevant articles and documents

An air-stable cationic iridium hydride as a highly active and general catalyst for the isomerization of terminal epoxides

We describe the use of an air-stable iridium hydride catalyst for the isomerization of terminal epoxides into aldehydes with perfect regioselectivity. The system operates at low loadings of catalyst (0.5 mol%), is highly practical, scalable, and tolerates functional groups that would not be compatible with Lewis acids typically used in stoichiometric amounts. Evidence for a rare hydride mechanism are provided. This journal is the Partner Organisations 2014.

Isomerization of terminal epoxides by a [Pd-H] catalyst: A combined experimental and theoretical mechanistic study

An unusual palladium hydride complex has been shown to be a competent catalyst in the isomerization of a variety of terminal and internal epoxides. The reaction displayed broad scope and synthetic utility. Experimental and theoretical evidence are provided for an unprecedented hydride mechanism characterized by two distinct enantio-determining steps. These results hold promise for the development of an enantioselective variant of the reaction.

Efficient Wittig-Horner Synthesis of Acyclic α-Enones with an Asymmetric Carbon at the γ-Position Using Barium Hydroxide

β-Monosubstituted acyclic α-enones with an asymmetric carbon at the γ-position: (E)-(5RS)-5-phenylhex-3-en-2-one, (4a), (E)-(6RS)-2,2-dimethyl-6-phenylhept-4-en-3-one, (4b), (E)-(4RS)-1,4-diphenylpent-2-en-1-one, (4c), (E)-(5RS)-6,6-dimethyl-5-phenylhept-