86477-17-0

Basic information

• Product Name: Benzene, 1,1'-(3-methoxy-1-propene-1,3-diyl)bis-
• CAS NO: 86477-17-0
• Molecular Formula: C16H16O
• Molecular Weight: 224.302
• Mol File: 86477-17-0.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(3-methoxy-1-propene-1,3-diyl)bis-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(3-methoxy-1-propene-1,3-diyl)bis-(86477-17-0)
• EPA Substance Registry System: Benzene, 1,1'-(3-methoxy-1-propene-1,3-diyl)bis-(86477-17-0)

Safety Data

• Hazardous Substances Data: 86477-17-0(Hazardous Substances Data)

Upstream product

• 94-41-7 benzalacetophenone 
• 67-56-1 methanol 
• 4663-33-6 1,3-diphenyl-3-hydroxypropene 
• 98-86-2 acetophenone 
• 100-52-7 benzaldehyde 
• 73930-97-9 3-acetoxy-1,3-diphenylpropene 
• 74-88-4 methyl iodide 
• 62668-02-4 (E)-1,3-diphenyl-2-propen-1-ol 
• 281190-31-6 C₁₈H₂₀O 
• 3780-00-5 1-(3-phenyl-1,2-propadienyl)benzene 
• 124-41-4 sodium methylate 

Downstream Products

• 112529-01-8 2,4-diphenylbut-3-enenitrile 
• 112529-04-1 hexa-1,5-diene-1,3-diyldibenzene 
• 3412-44-0 (1E)-1,3-diphenylpropene 
• 94-41-7 benzalacetophenone 
• 1258303-01-3 C₂₃H₂₈O 
• 1401009-12-8 C₁₉H₂₃O₃PS 
• 281190-31-6 C₁₈H₂₀O 
• 22719-64-8 1.3.5.5-Tetraphenyl-5-methoxy-penten-⁽¹⁾ 

Relevant articles and documents

Direct Reduction of Allylic Alcohols Using Isopropanol as Reductant

The lithium cation-catalyzed direct reduction of allylic alcohols to alkenes using isopropanol as a hydride donor was developed. The hydride transfer of the in situ-generated lithium isopropoxide to an allylic cation is the key process in this transformation. The reaction generates only water and acetone as byproducts, which highlights the synthetic utility of this method. (Figure presented.).

HBF4-Catalysed Nucleophilic Substitutions of Propargylic Alcohols

The activity of HBF4 (aqueous solution) as a catalyst in propargylation reactions is presented. Diverse types of nucleophiles were employed in order to form new C-O, C-N and C-C bonds in technical acetone and in air. Good to excellent yields and good chemoselectivities were obtained using low acid loading (typically 1 mol-%) under simple reaction conditions. The activity of HBF4 (aq. solution) as a catalyst in propargylation reactions is presented. C-O, C-N and C-C bonds were formed in technical acetone and in air. Good to excellent yields were obtained using low acid loading (typically 1 mol-%) under mild reaction conditions.

Efficient assembly of α-aryl and α-vinyl nitriles via iron-catalyzed ether bond activation

A novel and practical method for the synthesis of diverse α-aryl and α-vinyl nitriles was developed via an iron-catalyzed sp3 C-O ether bond cleavage with C-C bond formation in the reaction of π-activated ethers with TMSCN.