86517-23-9

Basic information

• Product Name: (2S,3S)-2,3-Di-morpholin-4-yl-3-phenyl-propionaldehyde
• CAS NO: 86517-23-9
• Molecular Weight: 304.389
• Mol File: 86517-23-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2S,3S)-2,3-Di-morpholin-4-yl-3-phenyl-propionaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3S)-2,3-Di-morpholin-4-yl-3-phenyl-propionaldehyde(86517-23-9)
• EPA Substance Registry System: (2S,3S)-2,3-Di-morpholin-4-yl-3-phenyl-propionaldehyde(86517-23-9)

Safety Data

• Hazardous Substances Data: 86517-23-9(Hazardous Substances Data)

Upstream product

• 110-91-8 morpholine 
• 33603-90-6 (2Z)-2-bromo-3-phenyl-2-propenal 

Downstream Products

• 18940-24-4 (E)-2-Morpholin-4-yl-3-phenyl-propenal 
• 86517-27-3 (E)-2-Morpholin-4-yl-3-phenyl-propenal 

Relevant articles and documents

Reaction des amines secondaires avec les aldehydes α,β-dibromes. Preparation d'α,β-diaminoaldehydes derives du cinnamaldehyde et nouvelle voie d'acces aux diamino-1,2 ethylenes

Secondary amines react with α-bromocinnamaldehyde to yield various 2,3-bisdialkylamino-3-phenylpropanals.These diaminoaldehydes undergo two competitive rections respectively leading to α-aminocinnamaldehyde and 1,2-diamino-ethylene.Experimental conditions selectively yielding one of these compound have been studied.With 2,3-dibromobutanal the same reaction does not afford diaminoaldehyde but 1,2-diaminoethylene and a new compound, 1,2,3-triamino-1-butene.A possible reaction mechanism is discussed and a new, general one-pot synthesis of 1,2-diaminoethylene from 2-butenal with good yields is described.