86563-22-6Relevant articles and documents
SYNTHESIS, PHYSICAL PROPERTIES AND SPECTROSCOPY OF Pd(II) COMPLEXES WITH CH3OOCCSNH2
Jacobs, Patrick,Dimitrou, Katerina,Perlepes, Spiros P.,Plakatouras, John,Desseyn, Herman O.
, p. 901 - 922 (2007/10/02)
The new complexes trans.0.5H2O, trans (X = Br, I, SCN), , cis (X = NCS, ONO2) and X2 (X = Cl, ClO4), where HL = H2NCSC'OOCH3, have been prepared.The complex trans was also isolated for comparison reasons.The complexes were characterized by elemental analyses, conductivity measurements, X-ray powder patterns, TG/DTG studies and spectral ((1)H-NMR electronic, IR and far-IR, Raman) studies.The vibrational analysis of the complexes is also given using deuterium isotopic substitutions.Monomeric square planar structures are assigned for the 1:2 and 1:4 complexes in the solid state ; the 1:1 nitrato complex is a polymer containing both monodentate and bidentate bridging nitrato groups.The thioamide sulfur atom of HL is the donor atom to PdII) and Pt(II).The thiocyanate ions are coordinated through sulfur in the trans complex and through nitrogen in the cis product.This differentiation on the mode of thiocyanate bonding is discussed.