866252-03-1 Usage
Description
(E)-[2-(phenylazo)phenyl]boronic acid is a chemical compound that belongs to the class of boronic acids. It is characterized by its unique structure, which includes a boronic acid group and an azobenzene group. This structure endows it with interesting properties for various applications, making it an important chemical in the field of organic chemistry.
Uses
Used in Organic Synthesis:
(E)-[2-(phenylazo)phenyl]boronic acid is used as a building block in the synthesis of various functional molecules. Its versatile nature allows for the creation of a wide range of compounds with different properties and applications.
Used in Suzuki-Miyaura Coupling Reactions:
In the field of organic chemistry, (E)-[2-(phenylazo)phenyl]boronic acid is used as a reagent for Suzuki-Miyaura coupling reactions. These reactions are crucial for the formation of carbon-carbon bonds, which are essential in the construction of complex molecular structures.
Used in Material Development:
(E)-[2-(phenylazo)phenyl]boronic acid has been studied for its potential applications in the development of new materials. Its unique structure and properties make it a promising candidate for the creation of innovative materials with specific characteristics.
Used in Pharmaceutical Research:
(E)-[2-(phenylazo)phenyl]boronic acid has also been explored for its potential use in the pharmaceutical industry. Its unique structure and reactivity may contribute to the development of new drugs or drug delivery systems.
Used in Molecular Electronics:
Due to its azobenzene group, (E)-[2-(phenylazo)phenyl]boronic acid has interesting properties for use in molecular electronics. It may be employed in the design and development of molecular-scale electronic devices and components.
Used as a Photoswitchable Compound:
The azobenzene group in (E)-[2-(phenylazo)phenyl]boronic acid allows it to function as a photoswitchable compound. This property can be exploited in various applications, such as in the development of light-responsive materials or systems that can be controlled by light stimuli.
Check Digit Verification of cas no
The CAS Registry Mumber 866252-03-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 8,6,6,2,5 and 2 respectively; the second part has 2 digits, 0 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 866252-03:
(8*8)+(7*6)+(6*6)+(5*2)+(4*5)+(3*2)+(2*0)+(1*3)=181
181 % 10 = 1
So 866252-03-1 is a valid CAS Registry Number.
866252-03-1Relevant articles and documents
Reversible Photoswitchable Inhibitors Generate Ultrasensitivity in Out-of-Equilibrium Enzymatic Reactions
Teders, Michael,Pogodaev, Aleksandr A.,Bojanov, Glenn,Huck, Wilhelm T. S.
supporting information, p. 5709 - 5716 (2021/05/07)
Ultrasensitivity is a ubiquitous emergent property of biochemical reaction networks. The design and construction of synthetic reaction networks exhibiting ultrasensitivity has been challenging, but would greatly expand the potential properties of life-like materials. Herein, we exploit a general and modular strategy to reversibly regulate the activity of enzymes using light and show how ultrasensitivity arises in simple out-of-equilibrium enzymatic systems upon incorporation of reversible photoswitchable inhibitors (PIs). Utilizing a chromophore/warhead strategy, PIs of the protease α-chymotrypsin were synthesized, which led to the discovery of inhibitors with large differences in inhibition constants (Ki) for the different photoisomers. A microfluidic flow setup was used to study enzymatic reactions under out-of-equilibrium conditions by continuous addition and removal of reagents. Upon irradiation of the continuously stirred tank reactor with different light pulse sequences, i.e., varying the pulse duration or frequency of UV and blue light irradiation, reversible switching between photoisomers resulted in ultrasensitive responses in enzymatic activity as well as frequency filtering of input signals. This general and modular strategy enables reversible and tunable control over the kinetic rates of individual enzyme-catalyzed reactions and makes a programmable linkage of enzymes to a wide range of network topologies feasible.
Photoswitching of the Lewis acidity of a catecholborane bearing an azo group based on the change in coordination number of boron
Kano, Naokazu,Yoshino, Junro,Kawashima, Takayuki
, p. 3909 - 3911 (2007/10/03)
(Chemical Equation Presented) Photoisomerization of a catecholborane bearing a 2-(phenylazo)phenyl group with an N-B dative bond caused photoswitching of the coordination number of boron between 3 and 4. The Lewis acidity of the catecholborane was switched by photoirradiation, and the complexation ability of the (E)- and the (Z)-isomers of the catecholborane with pyridine differs by more than a factor of 300.
