866457-94-5

Basic information

• Product Name: rac-(3-methyl-3-phenyloxiran-2-yl)methanol
• Synonyms: rac-(3-methyl-3-phenyloxiran-2-yl)methanol
• CAS NO: 866457-94-5
• Molecular Weight: 164.204
• Mol File: 866457-94-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: rac-(3-methyl-3-phenyloxiran-2-yl)methanol(CAS DataBase Reference)
• NIST Chemistry Reference: rac-(3-methyl-3-phenyloxiran-2-yl)methanol(866457-94-5)
• EPA Substance Registry System: rac-(3-methyl-3-phenyloxiran-2-yl)methanol(866457-94-5)

Safety Data

• Hazardous Substances Data: 866457-94-5(Hazardous Substances Data)

Upstream product

• 54976-38-4 (E)-3-phenylbut-2-en-1-ol 
• 54976-37-3 3-phenylbut-2-en-1-ol 
• 77-83-8 fraeseol 

Downstream Products

• 1189774-61-5 C₁₀H₁₀O₂ 

Relevant articles and documents

Manganese Catalyzed Hydrogenation of Enantiomerically Pure Esters

A manganese-catalyzed hydrogenation of esters has been accomplished with TONs up to 1000, using cheap, environmentally benign, potassium carbonate and simple alcohols as activator and solvent, respectively. The weakly basic conditions lead to good functional group tolerance and enable the hydrogenation of enantiomerically enriched α-chiral esters with essentially no loss of stereochemical integrity.

Enantioselective iminium-catalyzed epoxidation of hindered trisubstituted allylic alcohols

The reactivity of diastereomeric biaryl iminium cations made of a (Ra)-5,5′,6,6′,7,7′,8,8′-octahydrobinaphthyl core and exocyclic appendages derived from (S)- or (R)-3,3-dimethylbutyl-2-amine was investigated with hindered trisubstituted allylic alcohols