86654-32-2Relevant articles and documents
A supramolecular catalyst for the decarboxylative hydroformylation of α,β-unsaturated carboxylic acids
Smejkal, Tomas,Breit, Bernhard
, p. 3946 - 3949 (2008/12/23)
(Chemical Equation Presented) Head 'em up, move 'em out, aldehyde! A catalytic transformation of α,β-unsaturated carboxylic acids into aldehydes through a hydroformylation-decarboxylation process has been developed (see scheme; Do = donor ligand, FG1 and FG2 = complementary functional groups). The reaction proceeds at mild conditions, tolerates many functional groups, and liberates CO2 as the only stoichiometric by-product.
