867017-31-0

Basic information

• Product Name: 1-(dodecylsulfanyl)-4-methoxybenzene
• Synonyms: 1-(dodecylsulfanyl)-4-methoxybenzene
• CAS NO: 867017-31-0
• Molecular Weight: 308.528
• Mol File: 867017-31-0.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: 1-(dodecylsulfanyl)-4-methoxybenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(dodecylsulfanyl)-4-methoxybenzene(867017-31-0)
• EPA Substance Registry System: 1-(dodecylsulfanyl)-4-methoxybenzene(867017-31-0)

Safety Data

• Hazardous Substances Data: 867017-31-0(Hazardous Substances Data)

Upstream product

• 874-90-8 4-methoxybenzonitrile 
• 112-55-0 1-dodecylthiol 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 696-62-8 para-iodoanisole 
• 2757-37-1 didodecyl disulfide 
• 13139-86-1 4-methoxyphenyl magnesium bromide 
• 5335-87-5 4,4'-dimethoxyphenyl disulfide 
• 143-15-7 1-dodecylbromide 

Downstream Products

• 18272-84-9 4-n-butylanisole 
• 104-45-0 4-n-propylanisole 
• 4132-48-3 1-methoxy-4-(1-methylethyl)benzene 
• 613-36-5 4-cyclohexylanisole 

Relevant articles and documents

Ni-catalyzed C–S bond cleavage of aryl 2-pyridyl thioethers coupling with alkyl and aryl thiols

A nickel-catalyzed C–SPy bond activation reactions to produce a variety of thioethers has been developed. The reaction is promoted by a user-friendly, inexpensive, air and moisture-stable Ni precatalyst. Various aryl 2-pyridyl thioethers and a wide range of alkyl and aryl thiols substrates were tolerated in this process which afforded products in moderate to excellent yields.

CATALYTIC C-X-BOND METATHESIS THROUGH ARYLATION

The present invention refers to a process for a catalytic aryl transfer to rearrange the backbone of aromatic C-X bonds.

Microwave-Assisted Copper-Catalyzed Cross-Coupling Reaction of Thiols with Aryl Iodides in Water

Microwave-promoted C-S bond formation from thiols and aryl iodides in the presence of a copper catalyst is reported. A combination of copper(II) oxide and 1,10-phenanthroline catalyzes this reaction. A variety of aryl iodides react smoothly with thiols to provide the corresponding aryl sulfides in good to excellent yields. Notably, the reactions proceed in water with a short reaction time (30 minutes). This system shows broad functional-group tolerance; amino, chloro, bromo, acetyl, and nitro groups are unaffected by the reaction conditions.