867326-59-8

Basic information

• Product Name: [1-(tert-butyl-diphenyl-silanyloxymethyl)-2-(dimethyl-phenyl-silanyl)-2-oxo-ethyl]-carbamic acid tert-butyl ester
• Synonyms: [1-(tert-butyl-diphenyl-silanyloxymethyl)-2-(dimethyl-phenyl-silanyl)-2-oxo-ethyl]-carbamic acid tert-butyl ester
• CAS NO: 867326-59-8
• Molecular Weight: 561.869
• Mol File: 867326-59-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [1-(tert-butyl-diphenyl-silanyloxymethyl)-2-(dimethyl-phenyl-silanyl)-2-oxo-ethyl]-carbamic acid tert-butyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: [1-(tert-butyl-diphenyl-silanyloxymethyl)-2-(dimethyl-phenyl-silanyl)-2-oxo-ethyl]-carbamic acid tert-butyl ester(867326-59-8)
• EPA Substance Registry System: [1-(tert-butyl-diphenyl-silanyloxymethyl)-2-(dimethyl-phenyl-silanyl)-2-oxo-ethyl]-carbamic acid tert-butyl ester(867326-59-8)

Safety Data

• Hazardous Substances Data: 867326-59-8(Hazardous Substances Data)

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 145790-51-8 (S)-2-tert-butoxycarbonylamino-3-(tert-butyl-dimethyl-silanyloxy)-propionic acid 
• 3262-72-4 (S)-N-(tert-butoxycarbonyl)serine 
• 867326-58-7 [1-(tert-butyl-diphenyl-silanyloxymethyl)-2-imidazol-1-yl-2-oxo-ethyl]-carbamic acid tert-butyl ester 
• 3839-31-4 dimethyl(phenyl)silyllithium 

Downstream Products

• 867326-64-5 [1-(tert-butyl-diphenyl-silanyloxymethyl)-2-(dimethyl-phenyl-silanyl)-allylamino]-acetic acid methyl ester 
• 867326-62-3 1-(tert-butyl-diphenyl-silanyloxymethyl)-2-(dimethyl-phenyl-silanyl)-allylamine 

Relevant articles and documents

Chirality transfer in the aza-[2,3]-Wittig sigmatropic rearrangement

The aza-[2,3]-Wittig sigmatropic rearrangements of substrates derived from enantiomerically pure alanine, valine and serine with phenyl and ester anion stabilising groups were investigated for their efficiency in chirality transfer. It was found that a me