86747-85-5

Basic information

• Product Name: Tetramethylammonium methyl 4,6-O-benzylidene-2-deoxy-2-fluoro-β-D-glucopyranoside 3-sulfate
• Synonyms: Tetramethylammonium methyl 4,6-O-benzylidene-2-deoxy-2-fluoro-β-D-glucopyranoside 3-sulfate
• CAS NO: 86747-85-5
• Molecular Weight: 437.487
• Mol File: 86747-85-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Tetramethylammonium methyl 4,6-O-benzylidene-2-deoxy-2-fluoro-β-D-glucopyranoside 3-sulfate(CAS DataBase Reference)
• NIST Chemistry Reference: Tetramethylammonium methyl 4,6-O-benzylidene-2-deoxy-2-fluoro-β-D-glucopyranoside 3-sulfate(86747-85-5)
• EPA Substance Registry System: Tetramethylammonium methyl 4,6-O-benzylidene-2-deoxy-2-fluoro-β-D-glucopyranoside 3-sulfate(86747-85-5)

Safety Data

• Hazardous Substances Data: 86747-85-5(Hazardous Substances Data)

Upstream product

• 27994-50-9 Methyl 4,6-O-Benzylidene-β-D-manno-pyranoside 
• 373-68-2 tetramethylammonium fluoride 
• 88081-19-0 Methyl 4,6-O-Benzylidene-β-D-mannopyranoside 2,3-Cyclic Sulfate 

Downstream Products

• 86783-82-6 2-fluoro-D-glucose 
• 13242-55-2 2,3,4-tri-O-acetyllevoglucosan 

Relevant articles and documents

Cyclic Sulfur Esters as Substrates for Nucleophilic Substitution. A New Synthesis of 2-Deoxy-2-fluoro-D-glucose

The 2,3-cyclic sulfites and sulfates of methyl 4,6-O-benzylidene-α- and -β-D-mannopyranoside were synthesized and examined as suitable substrates for the preparation of 2-deoxy-2-fluoro-D-glucose.Both sulfites on reaction with tetramethylammonium fluoride gave reaction products due to attack at sulfur by water.The methyl α-D-glycoside sulfate gave an α,β-unsaturated ketone (7).The β-methyl sulfate reacted cleanly with fluoride and other nucleophiles to give, after hydrolysis, the 2-substituted 2-deoxyglucose compounds.