86762-94-9

Basic information

• Product Name: 2,4,6-Trimethoxy-2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)benzene
• Synonyms: 2,4,6-Trimethoxy-2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)benzene
• CAS NO: 86762-94-9
• Molecular Weight: 498.484
• Mol File: 86762-94-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,4,6-Trimethoxy-2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4,6-Trimethoxy-2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)benzene(86762-94-9)
• EPA Substance Registry System: 2,4,6-Trimethoxy-2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)benzene(86762-94-9)

Safety Data

• Hazardous Substances Data: 86762-94-9(Hazardous Substances Data)

Upstream product

• 82300-67-2 1-deoxy-1-(C-2',4',6'-trimethoxyphenyl) 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside 
• 74352-41-3 2-Pyridyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-galactopyranoside 
• 4291-69-4 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 
• 621-23-8 1,2,3-trimethoxybenzene 
• 604-68-2 α-D-glucopyranose peracetylate 
• 572-09-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide 
• 124754-17-2 Acetic acid (2R,3R,4S,5R,6S)-3,5-diacetoxy-2-acetoxymethyl-6-(4-methoxy-phenyltellanyl)-tetrahydro-pyran-4-yl ester 
• 108-24-7 acetic anhydride 
• 89648-16-8 β-D-glucopyranosyl-2,4,6-trimethoxybenzene 
• 1131-40-4 2-bromo-1,3,5-trimethoxybenzene 
• 78699-85-1 2,3,4,5,6-penta-O-benzyl-aldehydo-D-glucose 

Downstream Products

• 261956-02-9 1,3,5-trimethoxy-2-(2,3,4-tri-O-benzyl-β-D-xylo-hex-5-enopyranosyl)benzene 
• 891783-14-5 1,3,5-trimethoxy-2-(2,3,4-tri-O-acetyl-6-desoxy-6-iodo-β-D-glucopyranosyl)benzene 
• 891783-15-6 1,3,5-trimethoxy-2-(2,3,4-tri-O-acetyl-6-desoxy-β-D-xylo-hex-5-enopyranosyl)benzene 
• 89648-16-8 β-D-glucopyranosyl-2,4,6-trimethoxybenzene 

Relevant articles and documents

Application of the versatile character of the tellurium atom for the synthesis of C-nucleoside analogues via sugar tellurides

Making use of the versatile character of the tellurium atom such as its radicophilicity, nucleophilicity and electrophilicity, D-ribofuranosyl, 2-deoxy-D-ribofuranosyl and D-glucosyl p-methoxyphenyl tellurides have been prepared. Under suitable conditions, the corresponding anomeric radical, anomeric cation and anomeric anion, respectively, are formed from the sugar tellurides. By the following coupling reactions of the anomeric radical and anomeric cation to electron-poor and electron-rich aromatics, respectively, the corresponding C-nucleoside analogues have been synthesized in moderate yields. The anomeric anion has also been trapped by an electrophile such as benzaldehyde.

C-GLYCOSIDATION OF PYRIDYL THIOGLYCOSIDES

The pyridylthioglycosides 1 are efficiently transformed into the corresponding C-glycosides via reaction with silver(I) triflate and a variety of carbon nucleophiles.