86838-45-1Relevant articles and documents
Asymmetric synthesis of unsaturated α-benzyloxyaldehydes: An enantioselective synthesis of (+)-exo-brevicomin
Prasad, Kavirayani R.,Anbarasan, Pazhamalai
, p. 3951 - 3953 (2005)
Enantioselective synthesis of α-hydroxy aldehydes with an alkene tether was accomplished from l-(+)-tartaric acid, employing stereoselective reduction of a 1,4-diketone with L-selectride as the key step. Synthetic utility of these aldehydes was demonstrat
SYNTHESIS OF THE TWO ENANTIOMERIC FORMS OF 5-HEXADECANOLIDE PROPOSED PHEROMONE COMPONENT FROM VESPA ORIENTALIS
Servi, Stefano
, p. 2023 - 2024 (2007/10/02)
The first synthesis of R-(+)-5-hexadecanolide 1 and of it's S isomer 2 has been achieved in 9 steps, from the C4 chiral synthon 3; the absolute configuration is determined by conversion of the key intermediates 12 and 13 into R-and S-1,2-heptandiol.