86862-27-3

Basic information

• Product Name: Benzene, 1-nitro-3-(1,3,3,3-tetrachloropropyl)-
• CAS NO: 86862-27-3
• Molecular Formula: C9H7Cl4NO2
• Molecular Weight: 302.972
• Mol File: 86862-27-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, 1-nitro-3-(1,3,3,3-tetrachloropropyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-nitro-3-(1,3,3,3-tetrachloropropyl)-(86862-27-3)
• EPA Substance Registry System: Benzene, 1-nitro-3-(1,3,3,3-tetrachloropropyl)-(86862-27-3)

Safety Data

• Hazardous Substances Data: 86862-27-3(Hazardous Substances Data)

Upstream product

• 2547-61-7 Trichloromethanesulfonyl chloride 
• 586-39-0 1-nitro-3-vinyl-benzene 
• 56-23-5 tetrachloromethane 

Relevant articles and documents

Asymmetric Radical Reaction in the Coordination Sphere. III. Asymmetric Addition of Trichloromethanesulfonyl Chloride and Carbon Tetrachloride to Olefins Catalysed by a Ruthenium(II) Complex with Chiral Ligand

The asymmetric addition of trichloromethanesulfonyl chloride to styrene in the presence of a catalytic amount of ruthenium(II) complex with chiral ligands, Ru2Cl43 or Ru2Cl43, proceeds under mild conditions to give optically active 1:1 adducts, 1,1,1,3-tetrachloro-3-phenylpropane (2), with the extrusion of sulfur dioxide.When (-)-DIOP or (+)-DIOP was used as a chiral ligand of the ruthenium(II) complex, (R)-(+)-(2) or (S)-(-)-(2), was obtained with about 10percent enantiomeric excess, respectively.A reaction mechanism involving a radical redox transfer mechanism was proposed; the asymmetric induction was attributed to the restricted configuration of the radical intermediates confined in the coordination sphere of the ruthenium complex with chiral ligands.

ADDITION OF SULFONYL CHLORIDES TO OLEFINS IN THE PRESENCE OF CATALYTIC AMOUNTS OF DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)

Reactions of sulfonyl chlorides with olefins catalysed by dichlorotris(triphenylphosphine)ruthenium(II) have been studied.Methanesulfonyl and arenesulfonyl chlorides added to 1-alkenes to give 1 : 1 adducts in high yields.Telomer formation is not observed, therefore the present reaction provides a general and convenient method for synthesis of β-chlorosulfones.A radical-chain mechanism is proposed for the reaction.