86895-70-7

Basic information

• Product Name: methyl 2-phenylsulphinylhexanoate
• Synonyms: methyl 2-phenylsulphinylhexanoate
• CAS NO: 86895-70-7
• Molecular Weight: 254.35
• Mol File: 86895-70-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: methyl 2-phenylsulphinylhexanoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-phenylsulphinylhexanoate(86895-70-7)
• EPA Substance Registry System: methyl 2-phenylsulphinylhexanoate(86895-70-7)

Safety Data

• Hazardous Substances Data: 86895-70-7(Hazardous Substances Data)

Upstream product

• 109-65-9 1-bromo-butane 
• 14090-83-6 methyl 2-phenylsulfinylacetate 
• 75280-16-9 methyl 2-(phenylthio)hexanoate 
• 5445-19-2 methyl 2-bromohexanoate 
• 108-98-5 thiophenol 

Downstream Products

• 86895-82-1 methyl 2-ethyl-2-phenylthiohex-3-enoate 
• 86895-91-2 methyl 2-ethyl-4-phenylthiohex-2-enoate 
• 86895-75-2 (E)-methyl 2-phenylthiohex-2-enoate 
• 86895-74-1 (Z)-methyl 2-phenylthiohex-2-enoate 
• 75280-28-3 methyl 2-phenylthiohex-2-enoate 

Relevant articles and documents

Stereochemistry in the Knoevenagel Reaction of Methyl Arylsulphinylacetate and Aldehydes

The stereochemistry of the mechanism of the amine-catalyzed Knoevenagel reaction has been studied.Simple treatment of methyl arylsulphinylacetate (1) and aldehydes (2) with a catalytic amount of a secondary amine produced thermodynamically stable E-alkene

ALKYLATION OF EXTENDED ENOLATES FROM α-PHENYLTHIO CROTONATE ESTERS

Conditions are described for the formation of enolate anions from substituted α-phenylthio-crotonate esters and their alkylation at the α-carbon atom.