86952-05-8Relevant articles and documents
Desilylation and cyclometallation reactions of diphenylphosphine with platinum(II) compounds. Crystal structure of trans->
Al-Juaid, Salih S.,Eaborn, Colin,Hitchock, Peter B.,Smith, J. David,Zanotto, Livio,Kapoor, Pramesh N.
, p. 69 - 75 (2007/10/02)
The yellow complex trans- (L = PPh2CH(SiMe3)2) has been characterised.At attempt to make a similar complex with the more sterically hindered phosphine PPh2C(SiMe3)3 resulted in the loss of a trimethylsilyl group from one phosphine ligand and activation of a C-H bond in another to give the white complex , the structure of which was established by X-ray diffraction.
