869549-67-7

Basic information

• Product Name: [RuCl₂(As(C₆H₅)3)2(OC₆H₄CHNC₆H₁₁)]
• CAS NO: 869549-67-7
• Molecular Weight: 986.73
• Mol File: 869549-67-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [RuCl₂(As(C₆H₅)3)2(OC₆H₄CHNC₆H₁₁)](CAS DataBase Reference)
• NIST Chemistry Reference: [RuCl₂(As(C₆H₅)3)2(OC₆H₄CHNC₆H₁₁)](869549-67-7)
• EPA Substance Registry System: [RuCl₂(As(C₆H₅)3)2(OC₆H₄CHNC₆H₁₁)](869549-67-7)

Safety Data

• Hazardous Substances Data: 869549-67-7(Hazardous Substances Data)

Upstream product

• 61769-11-7 trichlorotris(triphenylarsine)ruthenium(III) 
• 19028-72-9 N-cyclohexylsalicylideneamine 

Relevant articles and documents

Synthesis, spectra, redox property and catalytic activity of ruthenium(III) Schiff base complexes

A series of ruthenium(III) complexes of the type [RuX2(EPh 3)2(L)] (where E= P or As, X= Cl or Br; L = bidentate Schiff bases) have been synthesized and characterized on the basis of analytical (elemental analysis, magnetic susceptibility) and spectral methods (FT-IR, UV-vis, EPR). EPR spectra of the powdered samples exhibit three lines with different 'g' values indicating a rhombic distortion in these complexes. Cyclic voltammogram of the complexes displays one reversible oxidation (Ru IV/RuIII) and two reversible reduction peaks (Ru III/RuII, RuII/RuI) with ΔEP=60-80 mV suggesting one electron transfer process. These complexes effectively catalyze the oxidation of primary alcohols to their corresponding aldehydes up to 91.5% in the presence of N-methylmorpholine-N- oxide (NMO) as co-oxidant. The formation of high-valent Run+2=O species as catalytic intermediate is proposed for the catalytic processes.